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Progress in Chemistry 2015, Vol. 27 Issue (4): 336-348 DOI: 10.7536/PC141010 Previous Articles   Next Articles

Special Issue: 锂离子电池

• Review and evaluation •

SiOx(0<x≤2) Based Anode Materials for Lithium-Ion Batteries

Liu Xin1, Zhao Hailei*1,3, Xie Jingying*2,4, Lv Pengpeng1, Wang Ke2, Cui Jiajia4   

  1. 1. School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China;
    2. Shanghai Institute of Space Power Sources, Shanghai 200245, China;
    3. Beijing Key Lab of New Energy Materials and Technology, Beijing 100083, China;
    4. Shanghai Engineering Center for Power and Energy Storage Systems, Shanghai 200245, China
  • Received: Revised: Online: Published:
  • Supported by:
    The work was supported by the National Key Basic Research Program of China (973 Program)(No. 2013CB934003), the National Natural Science Foundation of China (No. 21273019), the National High Technology Research and Development Program of China (863 Program)(No. 2013AA050902) , the Shanghai Science and Technology Talent Project Funds (No.12XD1421900), and the Shanghai Science and Technology Development Funds (No. 12dz1200503,13dz2280200).
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With rapidly growing application of lithium-ion batteries in electric vehicles and renewable energy storage, there is an increasing demand on high performance batteries in terms of energy density and power density. For anode materials, the traditional graphitized carbon materials cannot meet these requirements, novel high-capacity anode materials are being widely investigated, including Si-based materials. Among them, SiOx is considered to be a promising anode material for the practical use because it can deliver a high capacity and at the same time produce relatively lower volume change upon cycling compared to pure silicon. This paper summarizes the published works on SiOx-based anode materials. The basic electrochemical performance, structure model, electrochemical reaction mechanism and synthesis methods of SiOx powders are systematically reviewed. Methods used to improve electrochemical performance are classified and introduced, emphasized on those of SiO and amorphous SiO2. These works suggested that the oxygen content, disproportionation level and surface state of SiOx have significant influence on the electrochemical performance of SiOx. The interface clusters mixture (ICM) structural model can be used to better understand the nature of the electrochemical reaction processes of SiOx. Introduction of second phase (carbon, metals, metal oxides, etc.), preparation of porous structure, surface modification and optimization of binder and electrolyte are proved to be effective methods to improve the coulombic efficiency and cycling performance of SiOx electrode. Batteries with optimized SiOx-based material showed good cycling stability with 90% capacity retention after 600 cycles. SiOx-based composite is one of the best promising anode materials for lithium-ion batteries with high energy density.

Contents
1 Introduction
2 Properties of SiOx material
2.1 Basic electrochemical performance
2.2 Structure
2.3 Mechanism of the electrochemical process
2.4 Synthesis methods
3 SiOx-based materials
3.1 Compositing with second phase
3.2 Porous structured SiOx
3.3 Surface modification
3.4 Other factors and issues
4 Conclusion and outlook

Key words: SiOx, amorphous phase, composites, anode materials, lithium-ion batteries

CLC Number: 

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