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Progress in Chemistry 2015, Vol. 27 Issue (2/3): 297-309 DOI: 10.7536/PC140932 Previous Articles   Next Articles

Special Issue: 锂离子电池

• Review •

Nb-Based Oxides as Anode Materials for Lithium Ion Batteries

Lou Shuaifeng1, Cheng Xinqun1, Ma Yulin1, Du Chunyu1, Gao Yunzhi1, Yin Geping*1,2   

  1. 1. Institute of Advanced Power Sources, School of Chemical Engineering & Technology, Harbin Institute of Technology, Harbin 150001, China;
    2. State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150001, China
  • Received: Revised: Online: Published:
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No. 51472065).

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Li4Ti5O12 as anode materials for lithium ion batteries has been widely studied because of its excellent rate performance and cycle performance, but the low specific capacity (175 mAh/g) limits its application in the future. Compared with Li4Ti5O12, niobium based oxides have similar lithium ion insertion/extraction potential and higher specific capacity. In addition,they also have good rate performance and promising to be new anode materials with high power performance, that have got increasing researchers' attention in recent years. In this paper,the crystal structure, electrochemical performance and lithium ion insertion/extraction mechanism of various niobium based oxides materials (Nb2O5, TiNb2O7, LiNb3O8, etc.) are reviewed. The effects on lithium ion transfer and storage performance originate from component, particle morphology and preparation technology are discussed. Meanwhile, the influencing mechanism is also summarized. In addition, the generality in electrochemical lithium insertion and extraction behavior of niobium based oxides materials, the differences and similarities compared with Li4Ti5O12 are summarized the tendency and prospect of them as anode materials for high power lithium ion batteries in the end are also discussed.

Contents
1 Introduction
2 Research status of Nb-based oxides anode materials for lithium ion battery
2.1 Niobium oxides
2.2 Titanium niobium oxides
2.3 Lithium niobium oxides
2.4 Potassium niobium oxides
2.5 Vanadium niobium oxides
2.6 Other niobium based oxides
3 Understand of intercalation and deintercalation of lithium ion for niobium based oxide
4 Summary

Key words: lithium ion batteries, anode materials, Nb-based materials, mechanism of lithium insertion and extraction, electrochemical performance

CLC Number: 

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