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Progress in Chemistry 2015, Vol. 27 Issue (2/3): 157-167 DOI: 10.7536/PC140821 Previous Articles   Next Articles

• Review •

Photoresponsive Surfaces with Controllable Wettability

Zhan Yuanyuan1, Liu Yuyun1, Lv Jiuan1, Zhao Yong2, Yu Yanlei*1   

  1. 1. State Key Laboratory of Molecular Engineering of Polymers, Department of Materials Science, Fudan University, Shanghai 200433, China;
    2. School of Chemistry and Environment, Beihang University, Beijing 100191, China
  • Received: Revised: Online: Published:
  • Supported by:

    The work was supported by the State Key Program of National Natural Science of China(No. 21134003), the National Natural Science Foundation of China(No. 21273048), and the National Science Foundation for Distinguished Young Scholars of China (No. 51225304).

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Surface energy and surface topography are two key factors in the wettability of solid substrates. The surface energy determines the contact angle (CA) of a liquid on a flat substrate and the geometrical factor enhances the wetting property for a hydrophilic surface (or non-wetting for a hydrophobic surface). Applying external stimuli is a valuable approach for rendering the change in surface chemistry and/or topography, and for driving the wettability transition of smart surfaces. This review describes the current state-of-the-art research on the reversibly switchable wettability of surface brought about by external stimuli, including surface conversion between superhydrophobicity and superhydrophilicity prepared from inorganic oxides or/and photoactive organic molecules, movement of liquid droplets driven by molecular machines, and light-driven switching of superhydrophobic adhesion.

Contents
1 Introduction
1.1 Basic theory of surface wettability
1.2 Photoresponsive materials
2 Inorganic-oxide-based photoresponsive surfaces
3 Organic-compound-based photoresponsive surfaces
3.1 Non-azobenzene compound photoresponsive surfaces
3.2 Azobenzene compound photoresponsive surfaces
4 Conclusion

Key words: wetting property, contact angle, photoresponsive, superhydrophobicity, superhydrophilicity

CLC Number: 

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