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Progress in Chemistry 2015, Vol. 27 Issue (2/3): 146-156 DOI: 10.7536/PC140804 Previous Articles   Next Articles

• Review •

External Stimuli Regulated Surface-Initiated Atom Transfer Radical Polymerization

Li Bin1,2, Yu Bo1, Ye Qian1, Zhou Feng*1   

  1. 1. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;
    2. University of Chinese Academy of Sciences, Beijing 100049, China
  • Received: Revised: Online: Published:
  • Supported by:

    The work was supported by the Key Research Program of the Chinese Academy of Sciences (No.KJZD-EW-M01), the National Science Foundation for Distinguished Young Scholars of China (No. 21125316) and the National Natural Scence Foundation of China(No. 21204095).

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Surface-initiated atom transfer radical polymerization (SI-ATRP) has become an indispensable tool for tailoring of structures and properties of the polymer/inorganic and polymer/organic surfaces. However, traditional SI-ATRP always suffers from limitations such as rigorous synthetic protocols, heavy consumption of monomers and limited ability to control the polymerization process. Recently, many efforts have been taken to dramatically increase the scope of living radical polymerization through the development of new strategies to regulate the activation and deactivation steps by using a wide range of external stimuli, including electrochemistry, light and chemical reagent. We expect that this review will present a broad introduction to the field of the SI-ATRP research.

Contents
1 Introduction
2 Surface-initiated atom transfer radical polymerization(SI-ATRP)
2.1 Initiation
2.2 Propagation
2.3 Termination
3 New methods for SI-ATRP
3.1 Electrochemically mediated ATRP
3.2 Photochemically mediated ATRP
3.3 Chemicals mediated ATRP
4 Characterization of the polymer brush
5 Conclusion

Key words: surface-initiated polymerization, atom transfer radical polymerization (ATRP), external stimuli, polymer brush

CLC Number: 

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