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Progress in Chemistry 2014, Vol. 26 Issue (11): 1772-1780 DOI: 10.7536/PC140720 Previous Articles   Next Articles

Special Issue: 锂离子电池

• Review •

Characteristic of Gas Evolution in Lithium-Ion Batteries Using An Anode Based on Lithium Titanate

Wang Qian1,2, Zhang Jingze*1,2, Lou Yuwan1, Xia Baojia1   

  1. 1. Shanghai Institute of Microsystem and Information Technology, Shanghai 200050, China;
    2. University of Chinese Academy of Sciences, Beijing 100049, China
  • Received: Revised: Online: Published:
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No. 51277173, 21373257) and the Key Basic Research Programs of Science and Technology Commission of Shanghai Municipality(No.11JC1414600)

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At present, carbonaceous materials are extensively adopted as an anode for commercial lithium-ion batteries. Zero-strain lithium titanate is generally considered as a more safe and long-life span anode compared with carbonaceous materials, and it will find specific applications in various fields such as hybrid electric vehicles, wind-light-electricity grids, and smart grids. However, the lithium-ion batteries using the lithium titanate as anode will easily swell during the charge-discharge cycle and storage, thus resulting in shell distortion, gas evolution, performance deterioration, and so on. This greatly prevents the practical application of lithium titanate.In this paper, the industrial developments of the four kinds of lithium-ion batteries using the lithium titanate anode are reviewed, and the associated cathode materials are Li (Nix Coy Mn1-x-y) O2, LiMn2O4, LiFePO4, and LiCoO2, respectively. The latest research progress of the gas evolution mechanism is summarized from the perspectives of the interfacial characteristics, the water content, the electrolyte reductive decomposition, the negative electrode potential, and the impurities. At the same time, combined with the author's research work, the improving measures are put forward from the viewpoints of material, process, and application. Finally, the key issues and prospects of gassing are also commented.

Contents
1 Introduction
2 Industry status of lithium ion battery using lithium titanate as anode materials
3 Interface properties of lithium titanate material
4 The mechanism of gas evolution in lithium-ion batteries using an anode based on lithium titanate
4.1 Moisture
4.2 In the decomposition of electrolyte solution of lithium titanate electrode surface
4.3 Gas evolution reaction and the negative electrode potential
4.4 Impurities
5 Method to suppress gas evolution in lithium-ion batteries using an anode based on lithium titanate
5.1 Remove water or acid
5.2 Optimization of electrolyte
5.3 Surface treatment of lithium titanate material
5.4 Battery temperature and gas evolution
5.5 Optimization of lithium titanate battery manufacture process
6 Conclusion and outlook

Key words: lithium titanate, lithium-ion battery, gas evolution, mechanism, improvement

CLC Number: 

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