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Progress in Chemistry 2014, Vol. 26 Issue (12): 1914-1923 DOI: 10.7536/PC140647 Previous Articles   Next Articles

• Review •

Effects of Different Doping Sites on the Structure and Performance of Li4Ti5O12 Material

Huang Zhao1, Wang Dan2, Zhang Chunming*2, He Dannong*1,2   

  1. 1. School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China;
    2. National Engineering Research Center for Nanotechnology, Shanghai 200241, China
  • Received: Revised: Online: Published:
  • Supported by:

    The work was supported by the Shanghai Rising Star Program (No. 14QB1402900), the National Natural Science Foundation of China (No. 21171116) and the International Science & Technology Cooperation Program of China (No. 2012DFG11660)

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Li4Ti5O12 has the advantages of resource, performance, and so on. Recently, Li4Ti5O12 anode material is becoming an important research direction in the field of energy storage and power battery. In this review, the effects of doping ions with the different doping sites in the crystal lattice and its intrinsic properties on the structure and performance of Li4Ti5O12 were discussed. Substitution of doping ions for Li ions on the tetrahedral 8a sites would lower the Li-ion conductivity. Substitution of doping ions for Li ions on the octahedral 16d sites may "correct" distribution of alkali metal ions. Substitution of doping ions for Ti ions on the octahedral 16d sites would affect structural stability of Li4Ti5O12. Substitution of doping ions for O ions on the octahedral 32e sites would affect the conductivity. In certain conditions, if the valence state of doping ions is higher than the substituted ions, the electronic conductivity of Li4Ti5O12 could be improved. Doping elements with different energy band structures and redox behaviors affect the electrochemical reaction process of Li4Ti5O12. The different ionic radius and the number allowed to enter the lattice of doping ions would change the Li4Ti5O12 lattice constant and microstructure morphology.

Contents
1 Introduction
2 Structure properties of Li4Ti5O12
3 Doping of Li4Ti5O12
3.1 Position of dopants
3.2 Properties of dopants
3.3 Atmosphere of doping
4 Latest developments
5 Conclusion and outlook

Key words: ion doping, Li4Ti5O12, anode materials, Li-ion battery

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