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Progress in Chemistry 2014, Vol. 26 Issue (09): 1586-1595 DOI: 10.7536/PC140456 Previous Articles   Next Articles

Special Issue: 锂离子电池

• Review •

SnS2 Based Anode Materials for Lithium-Ion Batteries

Liu Xin1, Zhao Hailei*1,3, Xie Jingying*2, Wang Ke2, Lv Pengpeng1, Gao Chunhui1   

  1. 1. School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China;
    2. Shanghai Institute of Space Power Sources, Shanghai 200245, China;
    3. Beijing Key Lab of New Energy Materials and Technology, Beijing 100083, China
  • Received: Revised: Online: Published:
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No. 21273019), the National Key Basic Research Program of China (973 Program) (No.2013CB934003), the National High Techndogy Research and Development Program of China (863 Program) (No. 2013AA050902), the Shanghai Science and Technology Talent Project Funds (No.12XD1421900) and the Shanghai Science and Technology Development Funds (No. 12dz1200503, 13dz2280200)

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With the expanding of lithium-ion battery applications, novel cathode/anode materials with high capacity, long cycle life and excellent rate capability are in great demand. SnS2 is deemed to be one of potential alternative anode materials for its unique layer structure and high theoretical capacity. However, it suffers from large initial irreversible capacity, low electrical conductivity and huge volume change during charge/discharge process, which limit its practical application. In the present paper, the development history and latest progress of SnS2 anode material are reviewed. The basic properties of SnS2 are described. The approaches for improving the electrochemical performance of SnS2 are summarized, including micromorphology control of nanoparticles, preparation of SnS2/C and SnS2/oxide composites, bulk-doping, making integrative electrode, optimizing binder, etc. The influences of processing parameters (raw material, concentration, ratio, pH value, hydrothermal temperature and time) of hydrothermal (solovthermal) methods on the structure and electrochemical performance of the prepared SnS2 and SnS2/C composites are expounded. Besides, the problems associated with SnS2 anode materials are also discussed. Nanostructured SnS2 with high specific area, such as sheet- and flowerlike-shaped particles, is proved to be beneficial for cycle performance. Compositing SnS2 with different kinds of carbon can enhance the structure stability as well as electrical conductivity, and hence improve the cycle performance and rate capability of electrode. The optimized SnS2/graphene composite exhibits high specific capacity (over 1000 mAh/g), stable cycling performance and excellent rate capability, which make it a promising high capacity anode material for lithium-ion batteries.

Contents
1 Introduction
2 Basic properties of SnS2 anode materials
3 Approaches for improving the electrochemical performance of SnS2 materials
3.1 Early studies
3.2 Micromorphology control of SnS2 nanomaterials
3.3 SnS2/C composite materials
3.4 Other methods
4 Conclusion and outlook

Key words: SnS2, hydrothermal (solovthermal) method, composite, graphene, anode materials, lithium ion batteries

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