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Progress in Chemistry 2014, Vol. 26 Issue (06): 919-930 DOI: 10.7536/PC131240 Previous Articles   Next Articles

• Review •

Function and Application of Supramolecular Gels：Chiral Molecular Recognition and Asymmetric Catalysis

Jin Qingxian1, Li Jing1, Li Xiaogang1, Zhang Li2, Fang Shaoming*1, Liu Minghua*2   

  1. 1. Henan Provincial Key Laboratory of Surface and Interface Science, School of Materials and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, China;
    2. CAS Key Laboratory of Colloid Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • Received: Revised: Online: Published:
  • Supported by:

    The work was supported by the Doctoral Science Research Foundation of Zhengzhou University of Light Industry (No.2013BSJJ020)

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Supramolecular gel is an important class of soft materials, in which the solvents are immobilized by the entangled three-dimensional network formed by gelator molecules via the various non-covalent interactions. Supramolecular gel can be quickly formed, self-assembled into uniform and adjustable nanostructure over a wide scale range. Thus the research of supramolecular gel is one of the important research directions among supramolecular chemistry, nanotechnology and materials science. The functional gels are applied widely in many fields, such as material templates, photoelectric switch, drug release, molecular recognition, supramolecular catalysis, etc. With solid-liquid phase transition, controlled self-assembly and other characteristics, the supramolecular gel has become an important vehicle of the reserch of supramolecular chirality and molecular chirality. In recent years, the supramolecular gel has been applied to supramolecular asymmetric catalysis and chiral molecular recognition. And a series of important breakthroughs have been achieved. The new functional application of supramolecular gels have been established, and supramolecular gels have become an important means and method for preparation of chiral nano-materials.The chiral supramolecular gels, as a kind of soft materials will have potential application in the field of asymmetric catalysis and chiral recognition. The supramolecular gels may provide a high density of recognition or catalytic sites and chiral microenvironment suitable for recognition and asymmetric reaction, thus, the study of asymmetric catalysis and enantioselective recognition in the supramolecular gels becomes a hot issue and has attracted more and more attention in recent years.In this paper,the application of supramolecular gels on asymmetric catalysis and chiral recognition are reviewed mainly.

Contents
1 Introduction
2 Application of supramolecular gels in chiral molecular recognition
2.1 Chiral molecular recognition based on gel phenomenon
2.2 Chiral molecular recognition based on fluorescence spectra
2.3 Chiral molecular recognition based on supramolecular chiral characterization
3 Application of supramolecular gels in asymmetric catalysis
3.1 Self-assembly strategies for asymmetric organocatalysis
3.2 Asymmetric catalysis in supramolecular gels
4 Conclusion and outlook

Key words: supramolecular gels, self-assembly, asymmetric catalysis, chiral recognition

CLC Number: 

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