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Progress in Chemistry 2014, Vol. 26 Issue (06): 996-1004 DOI: 10.7536/PC131231 Previous Articles   Next Articles

• Review •

Synthesis of Organic/Inorganic Hybrid Materials via Thiol-Ene/Yne Click Chemistry

Yang Zhenglong*, Xu Xiaoli, Zhao Yuxin   

  1. School of Materials Science and Engineering, Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, Tongji University, Shanghai 200092, China
  • Received: Revised: Online: Published:
  • Supported by:

    The work was supported by the National High Technology Research and Development Program of China (863 Program,No. 2012AA030303), the Fundamental Research Funds for the Central Universities (Tongji University) (No. 0500219145), the Large Scale Equipment and Instruments in Tongji University Open Test Fund (No. 2012014), and the Key Basic Research Project of Shanghai Science and Technology Commission (No. 12JC1408600)

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During last several decades, organic/inorganic hybrid materials have been used widely in many fields due to their excellent structure and performance. Thiol-ene/yne click chemistry, a new type of click chemistry, is of great interest because of its mild reaction conditions, fast reaction rate, high yield, easy post-treatment and high selectivity for the obtained products. Therefore, synthesis of high-performance organic/inorganic hybrid materials via thiol-ene/yne click chemistry is one of the hot topics of novel material research. In this review, the recent research progress of organic/inorganic hybrid materials synthesized by thiol-ene/yne click chemistry is discussed. Synthesis of silicon-, carbon-, metal- and metal oxide-based organic/inorganic hybrid materials via thiol-ene/yne click chemistry is highlighted. In addition, the applications of these hybrid materials in the fields of biomedical materials, environment protection and photoelectric materials are summarized. Finally, the development trend and future prospects of organic/inorganic hybrid materials synthesized by thiol-ene/yne click chemistry are presented.

Contents
1 Introduction
2 Organic/inorganic hybrid materials synthesized by thiol-ene/yne click chemistry
2.1 Synthesis of silicon-based organic/inorganic hybrid materials
2.2 Synthesis of carbon-based organic/inorganic hybrid materials
2.3 Synthesis of metal- and metal oxide-based organic/inorganic hybrid materials
3 Application of organic/inorganic hybrid materials synthesized by thiol-ene/yne click chemistry
3.1 Biomedical materials
3.2 Environmental protection
3.3 Photoelectric materials
3.4 Other application
4 Conclusions and outlook

Key words: organic/inorganic hybrid materials, click chemistry, thiol-ene/yne, biomedical materials, environmental protection, photoelectric materials

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