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Progress in Chemistry 2014, Vol. 26 Issue (06): 961-975 DOI: 10.7536/PC131207 Previous Articles   Next Articles

• Review •

Iron-Based Inorganic Mesoporous Materials

Li Feihu*1,2, Nie Dongyang1   

  1. 1. School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, Jiangsu Engineering Technology Center for Environmental Purification Materials Research, Jiangsu Key Lab of Atmospheric Environment Monitor and Pollution Control, Nanjing 210044, China;
    2. Earth Science Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, U. S. A.
  • Received: Revised: Online: Published:
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No. 51002080, 51310105009), the China Scholorship Council(CSC) program(No.2011832032) and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)

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Iron-base inorganic mesoporous materials have attracted a lot of attentions recently due to their environmental-benignancy, cost-efficiency, and unique properties of magnetism and chemical activity, which allow them to find potential applications in different areas. In this paper, the recent progress in synthesis of iron-based inorganic mesoporous materials as well as their applications has been reviewed, with an emphasis on the synthetic routes and structural properties of various iron-based inorganic mesoporous materials (i.e., mesoporous iron oxyhydroxides, mesoporous iron oxides, mesoporous ferrosilicates, mesoporous iron phosphates, iron-based mesocrystals, mesoporous Fe/Si (C, Al, Ti) composites, etc.). In addition, their applications in catalysis, adsorption, gas-sensing, lithium-ion batteries, pharmacies, host-guest synthesis and other fields have been summarized and discussed. The current research problems of iron-based inorganic mesoporous materials and several future research directions have also been addressed.

Contents
1 Introduction
2 Synthesis of iron-based mesoporous materials
2.1 Mesoporous iron oxyhydroxides (MIHs)
2.2 Mesoporous iron oxides (MIOs)
2.3 Mesoporous ferrosilicates (MFSs)
2.4 Mesoporous iron phosphates (MIPs)
2.5 Iron-based mesocrytals (IMCs)
2.6 Mesoporous Fe/Si (C, Al, Ti) composites
2.7 Other iron-based mesoporous materials
3 Applications of iron-based mesoporous materials
3.1 Catalysis
3.2 Adsorption
3.3 Gas-sensing
3.4 Li-ion batteries
3.5 Pharmacies
3.6 Host-guest synthesis
3.7 Other applications
4 Summary

Key words: mesoporous, iron oxides, ferrosilicates, iron phosphate, iron-based mesocrystals

CLC Number: 

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Abstract

Iron-Based Inorganic Mesoporous Materials