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Progress in Chemistry 2014, Vol. 26 Issue (06): 939-949 DOI: 10.7536/PC131160 Previous Articles   Next Articles

Special Issue: 锂离子电池

• Review •

High Voltage Spinel-Structured LiNi0.5Mn1.5O4 as Cathode Materials for Li-Ion Batteries

Deng Haifu, Nie Ping, Shen Laifa, Luo Haifeng, Zhang Xiaogang*   

  1. College of Materials Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China
  • Received: Revised: Online: Published:
  • Supported by:

    The work was supported by the State Key Development Program for Basic Research of China (973 Program, No. 2014CB239701), the National Natural Science Foundation of China (No. 21173120, 51372116), the Natural Science Foundation of Jiangsu Province, China (No.BK2011030) and the Fundamental Research Funds for the Central Universities (No.NP2014403)

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Lithium ion batteries (LIBs) have been considered as promising energy storage devices in the past decades owing to their high operating voltage, large energy density and outstanding cycle performance. However, the currently commercial LIBs could not fulfill the demand of electric vehicles(EV) or hybrid electric vehicles(HEV) applications. Thence, superior electrode materials possessing either higher capacity or higher voltage have gained enormous interest. Taking this into account, spinel LiNi0.5Mn1.5O4 which owns high operating voltage, relatively high theoretical capacity (147 mAh ·g-1) and three-dimensional lithium ion transport channels has become one of the most excellent cathode materials. In the presented paper, the structure and synthesis of this material are reviewed, and special emphases are shown to the current research activities on LiNi0.5Mn1.5O4 cathodes in ion doping along with surface coating synthesized by various synthetic techniques. Finally, the key issues and prospects of the cathode material are commented.

Contents
1 Introduction
2 Structure of LiNi0.5Mn1.5O4 cathode material
3 Synthesis of LiNi0.5Mn1.5O4 cathode material
4 Problems of LiNi0.5Mn1.5O4 cathode material
5 Modification of LiNi0.5Mn1.5O4 cathode material
5.1 Ion doping
5.2 Surface modification
5.3 Other methods
6 Conclusions and outlook

Key words: LiNi0.5Mn1.5O4, rate capability, cycling stability, ion doping, surface modification

CLC Number: 

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