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Progress in Chemistry 2014, Vol. 26 Issue (05): 820-833 DOI: 10.7536/PC131145 Previous Articles   Next Articles

• Review •

Graphene and Its Composites in Sample Preparation

Han Qiang1,2, Wang Zonghua*2, Zhang Xiaoqiong1, Ding Mingyu*1   

  1. 1. Department of Chemistry, Tsinghua University, Beijing 100084, China;
    2. Laboratory of Fiber Materials and Modern Textile, the Growing Base for State Key Laboratory, Qingdao University, Qingdao 266071, China
  • Received: Revised: Online: Published:
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No.21075074,21275082, 81102411), the Natural Science Foundation of Qingdao (No.13-1-4-128-jch, 13-1-4-202-jch),the Natural Science Foundation of Shandong (No.ZR2011BZ004, ZR2011BQ005), JSPS and NSFC under the Japan-China Scientific Cooperation Program (No. 21111140014), the State Key Laboratory of Analytical Chemistry for Life Science (No. SKLACLS1110) and the National Basic Research Program of China(973 Program, Grant No. 2012CB722705)

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Sample preparation procedure is crucial for the sensitivity, selectivity and accuracy of the quantitative analysis. The exploration and study of new technologies and methods in sample preparation have become important subject and direction in current analytical chemistry owing to its significance. Sorption-based extraction techniques are currently the most widely applied sample preparation techniques. The core component of the sorption-based extraction techniques is adsorbent material, which dominates the selectivity and sensitivity of the method. Therefore, the development of new adsorbent materials is a hot research topic in sample preparation. As a novel class of carbonaceous nanomaterials, graphene has attracted considerable interest in many subjects due to its excellent physical and chemical properties. Remarkably, the superior merits of graphene, for instance, large specific surface area, good thermal and chemical stability, entirely lead to its numerous applications in separation science. This article focuses on the application of graphene and its composites in many sample preparation technologies (including solid-phase extraction, solid-phase microextraction, magnetic solid-phase extraction and other technologies) in order to monitor the trace substances in different matrices (such as environmental, food, biological samples and so on). Finally the existing problem of graphene in sample preparation is summarized, and the possible challenges and future perspectives in this field are also described.

Contents
1 Introduction
2 Graphene and its composites in sample preparation
2.1 Graphene and its composites in solid-phase extraction
2.2 Graphene and its composites in solid-phase microextraction
2.3 Graphene and its composites in magnetic solid-phase extraction
2.4 Graphene and its composites in sample preparation technologies
3 Conclusions and outlook

Key words: graphene, composites, sample preparation, solid-phase extraction, solid-phase microextraction, magnetic solid-phase extraction

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