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Progress in Chemistry 2014, Vol. 26 Issue (04): 682-694 DOI: 10.7536/PC130846 Previous Articles   

• Review •

Technique Progress and Chemical Mechanism Research of Tropospheric Peroxy Radical in Field Measurement

Li Xiaoqian1, Lu Keding2, Wei Yongjie1, Tang Xiaoyan*2   

  1. 1. State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012;
    2. State Key Joint Laboratory of Environment Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
  • Received: Revised: Online: Published:
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No.41005066) and the special fund of State Key Joint Laboratory of Envionment Simulation and Pollution Control(No.13K03ESPCP, 13Z02ESPCP)

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Peroxy radical chemistry is the main component of tropospheric chemistry, which is critical for the understanding of essential tropospheric issues such as atmospheric cleansing capacity, photochemical ozone production and secondary organic aerosol formations. Field measurements of peroxy radical concentrations and related analysis with observation based model are the prominent steps to foster the current understanding of peroxy radical chemistry. This paper reviews the state of measurement techniques for peroxy radical, extensively revisits the previous field studies with direct measurements of peroxy radical, outlins the peroxy radical concentrations reported in previous field observations, summarizes the tests of photochemical mechanism with direct field measurement results and discusses the major scientific findings achieved so far. Finally, an outlook for the new directions in the study of atmospheric peroxy radical chemistry is proposed.

Contents
1 Introduction
2 Measurement techniques of tropospheric peroxy radical
2.1 Matrix isolation electron spin resonance spectroscopy
2.2 Laser-induced florescence
2.3 Chemical amplification
2.4 Calibrations
3 Field measurement of peroxy radical
3.1 Field campaigns including peroxy radical measurement
3.2 Diurnal profiles and concentration levels of peroxy radical observed
4 Application of peroxy radical measurements in atmospheric chemical mechanism research
4.1 Peroxy radical chemical mechanism in background region
4.2 The response relationship between peroxy radical and NOx
4.3 The response relationship between peroxy radical and VOCs
4.4 Assessment of atmospheric chemical mechanism
5 Conclusions and outlook

Key words: peroxy radical, field measurement, measurement technique, chemical mechanism

CLC Number: 

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