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Progress in Chemistry 2014, Vol. 26 Issue (0203): 259-269 DOI: 10.7536/PC130767 Previous Articles   Next Articles

Special Issue: 锂离子电池

• Review •

Li-Rich Transition Metal Oxide xLi2MnO3·(1-x)LiMO2 (M=Ni, Co or Mn) for Lithium Ion Batteries

Bai Ying1,2, Li Yu1, Zhong Yunxia1, Chen Shi1,2, Wu Feng1,2, Wu Chuan*1,2   

  1. 1. Beijing Key Laboratory of Environmental Science and Engineering, School of Chemical Engineering & Environment, Beijing Institute of Technology, Beijing 100081, China;
    2. National Development Center for High Technology Green Materials, Beijing 100081, China
  • Received: Revised: Online: Published:
  • Supported by:

    This work was supported by the State Key Development Program for Basic Resarch of China (No.2009CB220100) and the Program for New Century Excellent Talents in University (No.NCET-12-0047)

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As a promising candidate of the cathode materials for the next generation of high energy density lithium-ion batteries, the Li-rich transition metal oxide xLi2MnO3 ·(1-x)LiMO2 (M=Ni, Co or Mn) is superior to the traditional cathode materials for its potential of achieving very high capacity of over 300mAh/g. Therefore, this type of materials is caught more and more attention in recent years. Here we give an overview of recent progress of xLi2MnO3 ·(1-x)LiMO2 in recent years. The research hotspots, the crystal structure characteristics and the mechanism of initial charge and discharge, the development of various synthesis methods, as well as the improvement of the electrochemical performances for xLi2MnO3 ·(1-x)LiMO2(M=Ni, Co or Mn) are commented. The future development trends of the xLi2MnO3 ·(1-x)LiMO2 (M=Ni, Co or Mn) is put forward.

Contents
1 Introduction
2 Research on initial charge-discharge mechanism of Li-rich composite cathode materials
2.1 Crystal structure of Li-rich composite cathode materials
2.2 Initial charge-discharge mechanism of Li-rich composite cathode materials
3 Synthesis methods for xLi2MnO3·(1-x)LiMO2
3.1 Co-precipitation method
3.2 Sol-gel method
3.3 Solid state method
3.4 Sucrose combustion method
3.5 Hydrothermal method
3.6 Low-temperature molten salt method
3.7 Other synthesis methods
4 Improvements on electrochemical properties of Li-rich composite cathode materials
4.1 Doping in the lattice
4.2 Surface coating
4.3 Doping other materials
4.4 Particle nanocrystallization and control of structures or morphologies of cathode materials
4.5 Proposing and exploration of new method
5 Conclusions and outlook

Key words: lithium-ion battery, cathode materials, transition metal oxide, high capacity, synthesis methods

CLC Number: 

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