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Progress in Chemistry 2014, Vol. 26 Issue (0203): 394-402 DOI: 10.7536/PC130759 Previous Articles   Next Articles

• Review •

Functional POSS-Containing Polymers and Their Applications

Zhang Kaiqiang1, Li Bo1, Zhao Yunhui*1, Li Hui1,2, Yuan Xiaoyan*1   

  1. 1. Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072;
    2. Shandong Key Laboratory of Fluorine Chemistry and Chemical Engineering Materials, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China
  • Received: Revised: Online: Published:
  • Supported by:

    The work was supported by the National Natural Science Foundation of China(No. 51273146, 51103061)

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Polyhedral oligomeric silsesquioxanes (POSS) are silsesquioxane molecules with a special cage-like nanoscaled organic/inorganic hybrid structure. Among them, octa-silsesquioxanes have been mostly investigated. Compared with other inorganic agents, the structure of a rigid, cubic inorganic silica core and eight corner organic groups endow POSS possesses unique physical properties and chemical reactivities. The corner substituents, identical or different, can be used to design and prepare POSS-containing hybrid polymers. Owing to the special structure, functional POSS-containing polymers can be prepared through physical mixing or chemical copolymerization. With the development of advanced polymer-synthesis methods including "click" chemistry, reversible addition-fragmentation chain transfer polymerization and atom transfer radical polymerization, well-defined POSS-containing hybrid polymers have been obtained, such as star-shaped, branch or block polymers, which has aroused extensive interests in recent years. Based on the nature of POSS, the main routes for synthesizing the functional POSS-containing polymers are briefly reviewed in this paper. Furthermore, applications of POSS-containing polymers are particularly introduced including constructing superhydrophobic films or surfaces for fabrics or anti-icing, developing amphiphilic polymers, and taking advantage of POSS as a building block for shape memory polymers. The challenges of POSS-containing polymers are also proposed based on the current progress. Finally, the research trends of the POSS-containing polymers are prospected.

Contents
1 Introduction
2 POSS-containing polymeric surfaces
2.1 Omniphobic POSS-containing polymers
2.2 POSS-containing coatings for anti-icing
3 Amphiphilic POSS-containing polymers
4 POSS-containing shape memory polymers
5 Conclusion

Key words: polyhedral oligomeric silsesquioxanes, superhydrophobic surface, anti-icing, amphiphilic polymer, shape memory polymer

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