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Progress in Chemistry 2014, Vol. 26 Issue (0203): 277-292 DOI: 10.7536/PC130646 Previous Articles   Next Articles

• Review •

Synthesis and Applications in Catalysis of Porphyrinic Metal-Organic Frameworks

Zhuang Changfu1,2,4, Liu Jianlu2, Dai Wen1,3, Wu Zhongping2, Wang Ying4, Gao Shuang*1   

  1. 1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;
    2. Shandong Haihua Group Corporation Ltd., Weifang 262737, China;
    3. University of the Chinese Academy of Sciences, Beijing 100039, China;
    4. Faculty of Materials Engineering, Southwest Forestry University, Kunming 650224, China
  • Received: Revised: Online: Published:
  • Supported by:

    This work was supported by the State Key Development Program for Basic Research of China (No.2009CB623505), the National Natural Science Foundation of China (No.21273225), and the China Postdoctoral Science Foundation (No.2013M541257)

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Heterogeneous catalysis is one of the promising applications for metal-organic frameworks (MOFs) materials because of their high porosity, large surface areas and their flexible tailoring. An attractive approach to design MOFs-based catalysts is to heterogenize them by employing known homogeneous molecular catalysts as struts. In view of the enormous utility as active sites in metallo-enzymes, metalloporphyrin is obvious candidates for incorporation into MOFs as catalytically functional struts. Many efficient strategies have been established for the rational design and synthesis of catalytically functional porphyrinic MOFs. This review is aimed to summarize recent progress on porphyrinic MOFs, including new synthesis strategies and applications in catalysis. The development trends of porphyrinic MOFs are also prospected.

Contents
1 Introduction
2 Synthesis strategies for porphyrinic MOFs
2.1 Utility of extendable porphyrinic ligands in generating secondary building units (SBUs)
2.2 Using specially designed spacers to stabilize secondary building units (SBUs)
2.3 Combination of mixed-ligands
2.4 Template-directed synthesis
3 Heterogeneous catalytic performances of porphyrinic MOFs
3.1 MOFs-based catalysts constructed by porphyrinic ligands
3.2 Catalytic reactions of MOFs-encapsulated porphyrinic catalysts
4 Conclusions and outlook

Key words: porphyrin, metal-organic frameworks, heterogeneous catalysis, synthesis

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