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Progress in Chemistry 2013, Vol. 25 Issue (06): 927-939 DOI: 10.7536/PC120854 Previous Articles   Next Articles

Special Issue: 锂离子电池

• Review •

MV3O8(M=Li+, Na+, NH4+) as Novel Intercalated Materials for Li-Ion Batteries

Wang Haiyan*, Tang Yougen, Zhou Donghui, Liu Suqin, Zhang Hui   

  1. Key Laboratory of Resources Chemistry of Nonferrous Metals, Ministry of Education, School of Chemistry and Chemical Engineering, Central South University, Changsha 410083
  • Received: Revised: Online: Published:
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Research progress of MV3O8 (M=Li+, Na+, NH4+) as lithium intercalated materials for lithium ion batteries in recent years are reviewed,especially with emphasis on their crystal structures, charge-discharge mechanisms, synthesis methods and electrochemical properties. The advantage and disadvantage of the involved three kinds of vanadium-related materials are well compared on the basis of our group's research. Till now, LiV3O8 has been widely studied and large progress has been made via employing the novel preparation strategies, effective doping or modification methods. However, the intrinsic inferior structure has become a big challenge for its further study and applications. Due to the relatively stable layered structure, NaV3O8 has good cycling stability and excellent rate capability, thus it exhibits a great potential to be used as a high-power and long-cycling life cathode material for non-aqueous lithium ion battery, as well as high performance anode material for aqueous lithium ion battery. In comparison with LiV3O8, NH4V3O8 shows comparable capacity, much easier preparation and better cycling stability probably due to its formation of intra molecular H-bond. It is believed that NH4V3O8 could become a new research topic in vanadates as intercalated materials for lithium ion batteries. Contents
1 Introduction
2 LiV3O8
2.1 Crystal structure
2.2 Charge-discharge mechanism of LiV3O8 used as cathode material for Li-ion battery
2.3 Synthesis methods
2.4 Effect factors of electrochemical performance
2.5 Modification studies
2.6 LiV3O8 as anode material for aqueous Li-ion battery
3 NaV3O8
3.1 Crystal structure
3.2 Charge-discharge mechanism of NaV3O8 used as cathode material for Li-ion battery
3.3 Synthesis and electrochemical performance
4 NH4V3O8
4.1 Crystal structure
4.2 Charge-discharge mechanism of NH4V3O8 used as cathode material for Li-ion battery
4.3 Synthesis and electrochemical performance
5 Conclusions and outlook

Key words: lithium ion batteries, LiV3O8, NaV3O8, NH4V3O8, electrochemical properties

CLC Number: 

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