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Progress in Chemistry 2013, Vol. 25 Issue (05): 726-734 DOI: 10.7536/PC120831 Previous Articles   Next Articles

• Review •

Chemical Synthesis of Molybdenum Disulfide and Its Applications as Hydrodesulphurization Catalysts

Liu Ning1, Wang Xuzhen*1,3, Xu Wenya1, Guo Decai2, Tang Jizhou2, Zhang Baolu2   

  1. 1. School of Chemistry, Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024, China;
    2. School of Chemical Engineering, Faculty of Chemical, Environmental and Biological Science and Technology, Dalian University of Technology, Dalian 116024, China;
    3. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
  • Received: Revised: Online: Published:
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Molybdenum disulfide (MoS2), as a classical layered transition-metal dichalcogenide, have attracted much attention in recent years because of their wide utilization in catalytic hydrogenation, lubrication and photoelectricity fields. Nano- or micro-meter scaled materials exhibit many excellent capabilities in virtue of their special microstructures. Therefore, it is particularly significant to give impetus to the research of inorganic layered compounds through the synthesis experience of nano-/micro-meter sized MoS2 materials with specific morphologies and structures. Based on the recently numerous reports about nano- or micro-meter scaled MoS2 and their applications in the relevant fields, this review focuses on the latest progress in chemical synthetic methods of MoS2 micro- or nano-particles and MoS2-based composites with different morphology and property, including thermal decomposition, sulfidation of molybdenum oxides, hydrothermal/solvothermal and solution routes, as well as other novel combined physical-chemical techniques. The effects of various reaction conditions on the morphology and performance of MoS2 products have been discussed, and the characteristics of various methods have also been commented. In addition, the applications of MoS2 used as unsupported or supported catalysts in hydrodesulphurization of fossil fuel have been introduced, and the developing tendency and future prospect of MoS2 materials are projected. Contents
1 Introduction
2 Properties and structure of MoS2
3 Preparation of MoS2
3.1 Thermal decomposition
3.2 Sulfidation of molybdenum oxides
3.3 Hydrothermal/solvothermal process
3.4 Liquid precipitation
3.5 Other chemical synthesis methods
4 Application of MoS2 in hydrodesulphurization
4.1 Supported MoS2 catalysts
4.2 Unsupported MoS2 catalysts
5 Summary and perspective

Key words: MoS2 nano-/micro-particles, chemical synthesis, hydrodesulphurization, catalytic performance

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