中文
Earlier issues
Announcement
More
Progress in Chemistry DOI: 10.7536/PC120621 Previous Articles   Next Articles

• Review •

Preparation and Properties of Separation Membranes for Vanadium Redox Flow Battery

Wang Nanfang1,2, Liu Suqin*2   

  1. 1. School of Chemistry and Chemical Engineering, Hunan Institute of Engineering, Xiangtan 411104, China;
    2. School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
  • Received: Revised: Online: Published:
PDF ( 1652 ) Cited
Export

EndNote

Ris

BibTeX

All vanadium redox flow battery (VRB) is accepted as a electrochemical energy storage device for the load levelling and peak shaving of the grid, the power supply for remote area, the charging power source for the electric vehicles, and the uninterruptible power supply. As one of the key components in VRB system, the membrane, in the terms of its structures and properties, is responsible for the efficiencies of the VRB. The ion conductivity and vanadium ions permeation of the membrane affect the voltage efficiency and coulombic efficiency of the battery, respectively. The chemical stability of the membrane determines the long-term performance and lifetime of the battery. This review mainly summarizes the preparation and properties of the fluorinated ionic exchange membranes, the non-fluorinated ionic exchange membranes, and the pore membranes. The promising research strategies are outlook. Contents
1 Introduction
2 Fluorinated ionic exchange membranes
2.1 Nafion membranes
2.2 PVDF grafted membranes
2.3 PTFE grafted membranes
3 Non-fluorinated ionic exchange membranes
3.1 Poly (aryl ether)s membranes
3.2 Other membranes
4 Pore separation membranes
5 Conclusion and outlook

Key words: vanadium redox flow battey, ionic exchange membrane, permeability of vanadium ions, transfer of water, chemical stability

CLC Number: 

[1] Sum E, Rychcik M, Skyllas-Kazacos M. Journal of Power Sources, 1985, 16(2): 85-95
[2] Sum E, Skyllas-Kazacos M. Journal of Power Sources, 1985, 15(2/3): 179-190
[3] Skyllas-Kazacos M, Rychcik M, Robins R G, Fane A G, Green M A. Journal of the Electrochemical Society, 1986, 133(5): 1057-1058
[4] Skyllas-Kazacos M, Rychick M, Robins R. US 4786567, 1986
[5] Sukkar T, Skyllas-Kazacos M. Journal of Membrane Science, 2003, 222(1/2): 235-247
[6] Mohammadi T, Skyllas-Kazacos M. Journal of Membrane Science, 1995, 107(1/2): 35-45
[7] Hwang G J, Ohya H. Journal of Membrane Science, 1997, 132(1): 55-61
[8] Li X, Zhang H, Mai Z, Zhang H, Vankelecom I. Energy & Environmental Science, 2011, 4: 1147-1160
[9] Schwenzer B, Zhang J, Kim S, Li L, Liu J, Yang Z. ChemSusChem, 2011, 4(10): 1388-1406
[10] 陈振兴 (Chen Z X), 唐新村 (Tang X C). 高分子电池材料(Polymeric Materials for Batteries). 北京:化学工业出版社 (Beijing: Chemical Industry Press), 2006
[11] 文越华 (Wen Y H), 张华民 (Zhang H M), 钱鹏 (Qian P), 衣宝廉 (Yi B L). 电池 (Battery), 2005, 35(6): 414-416
[12] Luo Q T, Zhang H M, Chen J, Qian P, Zhai Y F. Journal of Membrane Science, 2008, 311(1/2): 98-103
[13] Luo Q T, Zhang H M, Chen J, You D J, Sun C X, Zhang Y. Journal of Membrane Science, 2008, 325(2): 553-558
[14] Zeng J, Jiang C P, Wang Y H, Chen J W, Zhu S F, Zhao B J, Wang R. Electrochemistry Communications, 2008, 10(3): 372-375
[15] Schwenzer B, Kim S, Vijayakumar M, Yang Z, Liu J. Journal of Membrane Science, 2011, 372(1/2): 11-19
[16] Xi J Y, Wu Z H, Qiu X P, Chen L Q. Journal of Power Sources, 2007, 166(2): 531-536
[17] 滕祥国 (Teng X G), 赵永涛 (Zhao Y T), 席靖宇 (Xi J Y), 武增华 (Wu Z H), 邱新平 (Qi X P), 陈立泉 (Chen L Q). 化学学报 (Acta Chimica Sinica), 2009, 67(6): 471-476
[18] Teng X, Zhao Y, Xi J, Wu Z, Qiu X, Chen L. Journal of Power Sources, 2009, 189(2): 1240-1246
[19] Teng X, Zhao Y, Xi J, Wu Z, Qiu X, Chen L. Journal of Membrane Science, 2009, 341(1/2): 149-154
[20] Wang N, Peng S, Lu D, Liu S, Liu Y, Huang K. Journal of Solid State Electrochemistry, 2012, 16(4): 1577-1584
[21] 吕正中 (Lv Z Z), 胡嵩麟 (Hu H L), 罗绚丽 (Luo X L), 武增华 (Wu Z H), 陈立泉 (Chen L Q), 邱新平 (Qiu X P). 高等学校化学学报(Chemical Journal of Chinese Universities), 2007, 28(1): 145-148
[22] 龙飞 (Long F), 陈金庆 (Chen J Q), 王保国 (Wang B G). 天津工业大学学报 (Journal of Tianjin Polytechnic University), 2008, 27(4): 9-11
[23] Qiu J Y, Ni H F, Zhai M L, Peng J, Zhou H H, Li J Q, Wei G S. Radiation Physics and Chemistry, 2007, 76(11/12): 1703-1707
[24] Qiu J, Zhang J, Chen J, Peng J, Xu L, Zhai M, Li J, Wei G. Journal of Membrane Science, 2009, 334(1/2): 9-15
[25] Qiu J Y, Li M Y, Ni J F, Zhai M L, Peng J, Xu L, Zhou H H, Li J Q, Wei G S. Journal of Membrane Science, 2007, 297(1/2): 174-180
[26] Robeson L M, Matzner M. US 4380598, 1983
[27] Wang F, Hickner M, Kim Y S, Zawodzinski T A, McGrath J E. Journal of Membrane Science, 2002, 197(1/2): 231-242
[28] Ueda M, Toyota H, Ouchi T, Sugiyama J I, Yonetake K, Masuko T, Teramoto T. Journal of Polymer Science Part A: Polymer Chemistry, 1993, 31(4): 853-858
[29] Wang F, Hickner M, Ji Q, Harrison W, Mecham J, Zawodzinski T A, McGrath J E. Macromolecular Symposia, 2001, 175(1): 387-396
[30] Xing P X, Robertson G P, Guiver M D, Mikhailenko S D, Kaliaguine S. Polymer, 2005, 46(10): 3257-3263
[31] Chen D, Wang S, Xiao M, Meng Y. Journal of Power Sources, 2010, 195(7): 2089-2095
[32] Mai Z, Zhang H, Li X, Bi C, Dai H. Journal of Power Sources, 2011, 196(1): 482-487
[33] Gao Y, Robertson G P, Guiver M D, Jian X. Journal of Polymer Science Part A: Polymer Chemistry, 2003, 41(4): 497-507
[34] Gao Y, Robertson G P, Guiver M D, Jian X, Mikhailenko S D, Wang K, Kaliaguine S. Journal of Membrane Science, 2003, 227(1/2): 39-50
[35] Hwang G J, Ohya H. Journal of Membrane Science, 1998, 149(2): 163-169
[36] Hwang G J, Ohya H. Journal of Membrane Science, 1998, 140(2): 195-203
[37] Bae B, Hoshi T, Miyatake K, Watanabe M. Macromolecules, 2011, 44(10): 3884-3892
[38] Kerres J A. Journal of Membrane Science, 2001, 185(1): 3-27
[39] Xing D, Kerres J. Polymers for Advanced Technologies, 2006, 17(7/8): 591-597
[40] Arnold C Jr, Assink R A. Journal of Membrane Science, 1988, 38(1): 71-83
[41] Kim S, Yan J, Schwenzer B, Zhang J, Li L, Liu J, Yang Z, Hickner M A. Electrochemistry Communications, 2010, 12(11): 1650-1653
[42] Chen D, Wang S, Xiao M, Han D, Meng Y. Polymer, 2011, 52(23): 5312-5319
[43] Chen D, Wang S, Xiao M, Meng Y. Energy & Environmental Science, 2010, 3(5): 622-628
[44] Chen D, Wang S, Xiao M, Meng Y. Energy Conversion and Management, 2010, 51(12): 2816-2824
[45] Kashima G, Ibaraki K. EP 0790658A2, 1997
[46] 张守海 (Zhang S H), 邢东博 (Xing D B), 颜春 (Yan C), 蹇锡高 (Jian X G). 合成化学 (Chinese Journal of Synthetic Chemistry), 2007, 15(B11): 225-225
[47] Jian X G, Yan C, Zhang H M, Zhang S H, Liu C, Zhao P. Chinese Chemical Letters, 2007, 18(10): 1269-1272
[48] Ahmad H, Kamarudin S K, Hasran U A, Daud W R W. International Journal of Hydrogen Energy, 2010, 35(5): 2160-2175
[49] Chen D, Wang S, Xiao M, Han D, Meng Y. Journal of Power Sources, 2010, 195(22): 7701-7708
[50] Wang N, Peng S, Wang H, Li Y, Liu S, Liu Y. Electrochemistry Communications, 2012, 17(0): 30-33
[51] 桑商斌 (Sang S B), 黄可龙 (Huang K L), 石瑞成 (Shi R C), 王小波 (Wang X B). 中南大学学报:自然科学版 (Journal of Central South University(Science and Technology), 2005, 36(6): 1011-1016
[52] Hwang G J, Ohya H. Journal of Membrane Science, 1996, 120(1): 55-67
[53] Mohammadi T, Kazacos M S. Journal of Power Sources, 1996, 63(2): 179-186
[54] Tian B, Yan C W, Wang F H. Journal of Applied Electrochemistry, 2004, 34(12): 1205-1210
[55] 鲁丹(Lu D), 黄可龙 (Huang K L), 刘素琴( Liu S Q), 汪南方(Wang N F). 电源技术(Chinese Journal of Power Sources), 2012, 36(05): 655-657
[56] Huang K L, Li X G, Liu S Q, Tan N, Chen L Q. Renewable Energy, 2008, 33(2): 186-192
[57] 谭宁 (Tan N), 黄可龙 (Huang K L), 刘素琴 (Liu S Q). 电源技术 (Chinese Journal of Power Sources), 2004, 28(12): 775-778
[58] Chieng S C, Kazacos M, Skyllas-Kazacos M. Journal of Power Sources, 1992, 39(1): 11-19
[59] Chieng S C, Kazacos M, Skyllas-Kazacos M. Journal of Membrane Science, 1992, 75(1/2): 81-91
[60] Tian B, Yan C W, Wang F H. Journal of Membrane Science, 2004, 234(1/2): 51-54
[61] Hilal N, Al-Zoubi H, Darwish N A, Mohamma A W, Abu Arabi M. Desalination, 2004, 170(3): 281-308
[62] Zhang H, Zhang H, Li X, Mai Z, Zhang J. Energy & Environmental Science, 2011, 4(5): 1676-1679
[1] Mengrui Yang, Yuxin Xie, Dunru Zhu. Synthetic Strategies of Chemically Stable Metal-Organic Frameworks [J]. Progress in Chemistry, 2023, 35(5): 683-698.
[2] Zhang Huidi, Li Zijie, Shi Weiqun. The Stability Enhancement of Covalent Organic Frameworks and Their Applications in Radionuclide Separation [J]. Progress in Chemistry, 2023, 35(3): 475-495.
[3] . Bismuth (V)-Contained Semiconductor Compounds and Their Applications in Heterogeneous Photocatalysis [J]. Progress in Chemistry, 2010, 22(09): 1729-1734.