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化学进展 2007, Vol. 19 Issue (11): 1736-1745 前一篇   后一篇

• 综述与评论 •

N-羟基邻苯二甲酰亚胺及其类似物催化下的分子氧氧化反应

许海峰 唐瑞仁* 龚年华 刘长辉 周亚平   

  1. （中南大学化学化工学院 长沙 410083）
  • 收稿日期:2006-12-26 修回日期:2007-01-13 出版日期:2007-11-14 发布日期:2007-11-25
  • 通讯作者: 唐瑞仁
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Aerobic Oxidation Reactions Catalyzed by N-Hydroxyphthalimide and Its Analogues

xu haifeng; Tang Ruiren*; Gong Nianhua; Liu Changhui; Zhou Yaping   

  1. (School of Chemistry and Chemical Engineering, Central South University, Changsha 410083)
  • Received:2006-12-26 Revised:2007-01-13 Online:2007-11-14 Published:2007-11-25
  • Contact: Tang Ruiren
本文综述了近年来N-羟基邻苯二甲酰亚胺（NHPI）及其类似物催化下分子氧氧化的各种反应，并对它们的催化机理作了简要介绍。NHPI与过渡金属离子组成的催化体系能高效的催化乙烷氧化为乙酸、环烷烃氧化为二元羧酸、甲苯氧化为苯甲酸、烯烃氧化为环氧化物、炔烃氧化为炔酮、酰胺氧化为酰亚胺；NHPI单独使用能催化金刚烷发生氧化羰基化反应、催化氧化醇制取过氧化氢；NHPI与有机助催化剂如：偶氮二异丁腈、溴化季铵盐、蒽醌、醇等也能催化分子氧氧化反应。
关键词： N-羟基邻苯二甲酰亚胺, 自由基反应, 分子氧氧化, 催化氧化
This paper summarizes the recent aerobic oxidation reactions catalyzed by N-hydroxyph-thalimide(NHPI) and its analogues. The oxidation mechanism is also reviewed briefly. The catalytic system composed of NHPI and transition metal ion can catalyze effectively ethane into acetic acid , cyclane into dicarboxylic acid, toluene into benzoic acid，alkene into epoxide, alkyne into acetylenic ketone , and amide into imide; NHPI used alone can catalyze adamantane carbonylated, hydrogen peroxide prepared by oxidization alcohol; NHPI combined with assistant catalyst such as : azodiisobutyronitrile, quaternary ammonium bromide, anthraquinone, alcohol et.al can also catalyze aerobic oxidations.
Key words: N-hydroxyphthalimide(NHPI), free radical reaction, molecular oxygen oxidation, catalytic oxidation

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