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化学进展 2014, Vol. 26 Issue (10): 1665-1672 DOI: 10.7536/PC140637 前一篇   后一篇

• 综述与评论 •

氧气直接氧化苯制备苯酚

王伟涛*1, 姚敏2, 马养民1, 张金1   

  1. 1. 陕西科技大学化学与化工学院 教育部轻化工助剂化学与技术重点实验室 西安 710021;
    2. 西安凯立化工有限公司 西安 710016
  • 收稿日期:2014-06-01 修回日期:2014-07-01 出版日期:2014-10-15 发布日期:2014-08-12
  • 通讯作者: 王伟涛 E-mail:wangweitao@sust.edu.cn
  • 基金资助:

    陕西科技大学博士科研启动基金项目（No. BJ13-26, BJ12-26）资助

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导出 被引次数 ( 8 | 3 )

Direct Oxidation of Liquid Benzene to Phenol with Molecular Oxygen

Wang Weitao*1, Yao Min2, Ma Yangmin1, Zhang Jin1   

  1. 1. Key Laboratory of Auxiliary Chemistry and Technology for Chemical Industry of Ministry of Education, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China;
    2. Xi'an Catalyst Chemical Co., Ltd, Xi'an 710016, China
  • Received:2014-06-01 Revised:2014-07-01 Online:2014-10-15 Published:2014-08-12
  • Supported by:

    The work was supported by the Doctoral Starting up Foundation of Shaanxi University of Science & Technology (No. BJ13-26, BJ12-26)

苯酚是重要的化工原料，其工业生产主要是通过异丙苯氧化法制备，该方法存在制备流程长、消耗丙烯多以及产生大量副产物等不足。苯直接氧化制备苯酚，特别是氧气直接氧化苯制备苯酚，因其步骤少、操作成本低、环境友好等特点已成为苯酚绿色制备的研究热点。本文较为系统地总结了氧气氧化苯液相法合成苯酚的研究工作，综述了该反应体系下的反应机理以及所使用的催化剂、还原剂等；归纳了反应温度、反应压力、还原剂用量及反应溶剂等反应条件对苯酚产率的影响；分析了目前氧气直接氧化苯液相法制苯酚研究中存在的问题，并总结了未来的研究方向。

关键词： 苯, 氧气, 苯酚, 催化氧化

Phenol is a kind of important chemical materials, which is mainly produced from isopropylbenzene oxidation process. The drawbacks of the process include long synthesis process, consuming propylene and forming byproducts. Directly oxidation of benzene to phenol with molecular oxygen, possessing the advantages of less steps, low cost and environmental friendly, has become the research hotspot in green preparation of phenol. In this review, the progress of oxidation of liquid benzene to phenol with oxygen is summarized systematically. The reaction system, including the reaction mechanism, catalysts, and reductant is reviewed. The effects of reaction temperature, oxygen pressure, reductant and solvent on the yields of phenol are also discussed. Furthermore, the current research problems and future research perspectives are also suggested.

Contents
1 Introduction
2 Reaction mechanism
3 Catalysts
3.1 Vanadium-based catalysts
3.2 Copper-based catalysts
3.3 Heteropolyacids-based catalysts
3.4 Other catalysts
4 Reductants
5 The effects of reaction conditions
5.1 Reaction temperature
5.2 Reaction pressure
5.3 The account of reductant
5.4 Solvents
6 Conclusion and outlook

Key words: benzene, oxygen, phenol, catalytic oxidation

中图分类号: 

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摘要

氧气直接氧化苯制备苯酚