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化学进展 2007, Vol. 19 Issue (0203): 414-419 前一篇   后一篇

• 综述与评论 •

衰减全反射-紫外/可见光谱技术应用*

朱红祥1; 柴欣生1,2**;王双飞1;宋海农1;朱俊勇3   

  1. 1.广西大学 轻工与食品工程学院，南宁 530004;

    2.美国左治亚理工大学 造纸科学和技术研究所 Atlanta GA30332;

    3.美国农业部林业林产品实验室，Madison, WI53726

  • 收稿日期:2006-04-13 修回日期:2006-09-20 出版日期:2007-03-24 发布日期:2007-03-24
  • 通讯作者: 柴欣生
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Attenuated Total Reflection UV/Vis Spectroscopic Applications

Zhu Hongxiang1;Chai Xinsheng1,2**;Wang Shuangfei1;Song Hainong1;Zhu Junyong3   

  1. 1.School of Light Industrial and Food Engineering, Guangxi University, Nanning, Guangxi 530004, China;

    2. Institute of Paper Science and Technology, Georgia Institute of Technology, Atlanta, GA, 30332, USA;

    3.USDA Forest Product Laboratory,Madison,W153726,USA

  • Received:2006-04-13 Revised:2006-09-20 Online:2007-03-24 Published:2007-03-24
本文对衰减全反射法(ATR)的光学测定原理、衰减全反射-紫外/可见光谱方法（ATR-UV）的特点以及它们在一些典型的工业过程溶液，如高浓度和含有大量固体颗粒和微乳液聚合等体系检测的应用进行了综述。ATR-UV光谱技术适宜实时地反馈工业过程溶液的组分改变和浓度变化，从而帮助我们了解该过程的进展。这些优良的特性能帮助我们开发在线的传感器，因此可用于监测许多典型的工业过程溶液。其方法简单、迅速，一般无需对试样进行预处理或稀释。ATR-UV作为光谱学测定的重要波段，其技术开发将在化工过程检测方面具有重要的意义。
关键词： 衰减全反射法, 紫外/可见光谱, 传感器, 过程溶液
This paper describes the principle of attenuated total reflection(ATR) and the features of ATR-UV spectroscopy. It also provides a comprehensive review of the ATR-UV applications in several complicated streams, such as the solutions having very concentrated compositions or significant amount of suspended solids, and the latex of emulsion polymerization. The ATR-UV spectroscopic techniques is suitable to be developed as an on-line sensor for monitoring the species of interest in many typical industrial process streams ,which provides the real-time information that is very important for the process control. It is very simple and fast, and in general it dose not require sample pretreatment. As an important wavelength range in spectroscopy, the development of ATR-UV technology will be very helpful for not only the process monitoring but also the process study in the chemical engineering related fields.
Key words: attenuated total reflection (ATR), UV/Vis, spectroscopy, sensors, process liquor

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