Lin Mingzhang,Zhu Qingshi. Artificial Controlled Assembly of Metallic Nanoaggregates in Liquid Phase[J]. Progress in Chemistry, 1998, 10(03): 237-.
The study of metallic nanoaggregates and or clusters in liquid phase is one of the most important branches in modern chemistry and physics, and it is a complement to the study of nanoaggregates in gas phase or vacuum. Strongly in teracting with the medium , the system is very complicated; however, it is possible to control the size and structure of the particles. The study in this field is much more challenging and has potential applications. The ionizing irradiation induced or photochemical induced reduction of metallic ions has permitted us to prepare them etallic nanoaggregates in liquid phase. By optimizing the compositions and the properties of them edium (e. g. pH) , the size and size distribution of the particles have been under control, and the structure of the particles can also be controlled in the near future. Th is method has also other advantages such as narrow size distribution of particles, no chemical reductants and the possibility to prepare bimetallic nanoaggregates. Moreover, it is possible to do the fundamental studies on the formation of the metallic nanoaggregates by pulse irradiation, namely by pulse radiolysis.