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Progress in Chemistry 2020, Vol. 32 Issue (1): 84-92 DOI: 10.7536/PC190621 Previous Articles   Next Articles

Special Issue: 电化学有机合成

Silicon-Containing Functionalized Polyolefin: Synthesis and Application

Yongjie Zhang1,**(), Mingshuai Fan1, Xiaopei Li2, Huayi Li3, Shuwei Wang1, Wenqin Zhu4   

  1. 1. School of Textile and Material Engineering, Dalian Polytechnic University, Dalian 116034, China
    2. Instrumental Analysis Center, Dalian Polytechnic University, Dalian 116034, China
    3. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
    4. Petrochemical Research Institute, PetroChina, Beijing 102206, China
  • Received: Online: Published:
  • Contact: Yongjie Zhang
  • About author:
    ** E-mail: ;
  • Supported by:
    National Natural Science Foundation of China(21704009); Department of Education of Liaoning Province(J2017041); Department of Education of Liaoning Province(J2019046)
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Functionalization of polyolefin is an efficient route to new polymer materials with high performance/price ratio. Silicon-containing functional polyolefin (SFPO) is a kind of functional polyolefin that incorporate functional silicone groups or polysiloxane segments in the structure of polyolefin. Due to special physiochemical properties of silicone groups or polysiloxane, SFPO often possesses reactivity or advanced properties and forms a new group of functional polyolefin. SFPO can function as reactive intermediates in synthesizing functional polyolefins with complex topologies (star polymer, brush polymer and graft copolymer) or preparing polyolefin covalently grafted nanomaterials. SFPO can also serve as functional additives (compatibilizer, polymer process aid and surface modifier) in developing new polyolefin materials. In recent years, researchers have obtained a series of fruitful results on the syntheses and applications of SFPO. This review aims to cover the recent progress on SFPO, which we hope may arouse the attention of related researchers and promote further achievements in related research areas.

Key words: silicon-containing functionalized polyolefin, organosilicon functional group, polysiloxane, copolymer
Fig. 1 Synthetic routes and applications of TMS-PE and DMS-PE[24,25]
Fig. 2 Synthesis of low dispersity star PE with a Si-O-Si crosslinking core via a hydrolytic condensation process of TMS-PE[31]
Fig. 3 Polymer intrinsic viscosity as a function of molecular weight from tri-detector GPC analysis in trichlorobenzene at 150 ℃ (where α is the exponent in Mark-Houwink equation [η]=KM α,M LS refers to absolute M W determined by light scattering detectors)[31]
Fig. 4 Preparation of PE covalently grafted CNT via a combination of thiol-ene addition and hydrolytic co-condensation reactions (Inset: TEM graph of PE covalently grafted CNT; Scale bar: 50 nm)[32]
Fig. 5 Chain transfer agent (a) and co-monomers (b~f) used to synthesize polyolefins containing organosilicon functional groups[35,38,40,42~44]
Fig. 6 Synthesis of PP-g-PDMS via the coupling reaction between maleic anhydride grafted PP and monoaminopropyl terminated PDMS[49]
Fig. 7 The complex viscosity curves of pure PP, PP/MA-PP blend and PP/PP-g-PDMS blend
Fig. 8 Syntheses of well-defined PDMS-g-PE via a hetero-condensation reaction between DMS-PE and PDMS-diol[25]
Fig. 9 GPC curves of v-PE, DMS-PE, P(DMS-PE) and PDMS-g-PE[25]
Fig. 10 SEM micrographs of fracture faces of PE/silicone oil blends: LDPE/silicone oil blend (100/5, ×8000, a), LDPE/silicone oil/PDMS-g-PE (100/5/1, ×8000, b), HDPE/silicone oil blend (100/10, ×1000, c) and HDPE/silicone oil/LCAS blend (100/10/1,×1000, d)[25, 54,55]
Fig. 11 Synthetic route to long alkyl chain silicone (LCAS) via a siloxane equilibration process between commercially available AMS-C30 and silanol terminated siloxane oligomer[54,55]
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