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Progress in Chemistry 2019, Vol. 31 Issue (1): 201-209 DOI: 10.7536/PC180415 Previous Articles   Next Articles

Special Issue: 锂离子电池

• Review •

Silicon Nanoparticles/Carbon Composites for Lithium-Ion Battery

Zhenjie Li, Du Zhong, Jie Zhang, Jinwei Chen**(), Gang Wang, Ruilin Wang**()   

  1. College of Materials Science and Engineering, Sichuan University, Chengdu 610065, China
  • Received: Revised: Online: Published:
  • Contact: Jinwei Chen, Ruilin Wang
  • About author:
    ** Corresponding author e-mail: (Jinwei Chen);
    (Ruilin Wang)
  • Supported by:
    The work was supported by the Key R&D Project of Sichuan Province(No.2017GZ0397)(2017GZ0397); The Science and Technology Project of Chengdu City(2015-HM01-00531-SF)
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Silicon is expected to replace graphite as the next-generation anode material for lithium-ion batteries because of its high theoretical specific capacity. But the huge volume expansion (~300%) of silicon during lithiation/delithiation process will cause active substance pulverization and loss contact with current collector, and continuous formation of solid electrolyte layer will further result in irreversible capacity fading. It has been demonstrated that nanocrystallization and carbon coating are effective ways to overcome these problems. In this paper, the mechanism of capacity fading of silicon is introduced, and the latest research on the synthesis of Si nanoparticles and carbon composites is reviewed, mainly including coating, core-shell and embeded silicon/carbon anode materials. The core-shell and embedded type are specifically reviewed. Finally the problems of the Si nanoparticles/carbon composites are analyzed and the prospects for research are prospected.

Key words: lithium-ion battery, anode material, silicon/carbon composites, core-shell structure, embedded type
Fig.1 Failure mechanism of silicon electrode[20]
Fig.2 The critical dimension of silicon pulverization[21]
Fig.3 The production of nSi@rGS composites[45]
Fig.4 The production of CVS nano beads[56]
Fig.5 Diagram of Si-MCS[69]
Fig.6 The production of Si-rGO/NCT composites[81]
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