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Adsorption Mechanism of Macroporous Adsorption Resins

Lou Song1,2, Liu Yongfeng1,2, Bai Qingqing4, Di Duolong1,3,4   

  1. 1.Key Laboratory of Chemistry of Northwestern Plant Resources, Key Laboratory for Natural Medicines of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;
    2. Graduate University of Chinese Academy of Sciences, Beijing 100049, China;
    3. Centre of Resource Chemistry and New Materials, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Qingdao 266100, China;
    4. Key Laboratory of Chemistry and Quality for Traditional Chinese Medicines of the College of Gansu Province, Department of Pharmacy, Gansu College of Traditional Chinese Medicine, Lanzhou 730000, China
  • Received: Revised: Online: Published:
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Macroporous adsorption resins (MARs), which are synthetic porous crosslinked polymer beads, have been developed into a kind of novel functional materials since 1950’. They have widely been used in the fields such as pharmaceutical, chemical, food industries, and wastewater treatment. Besides the traditional research on applications of the commercial MARs in the enrichment process of target compound, some theoretical researches on the adsorption features of MARs are also introduced in this article, including adsorption isotherms, kinetics, driving forces, and interaction models. First, the adsorption isotherm patterns of target compound on MARs are discussed. Second, the diffusion patterns of targets on the surface and internal MARs are illustrated. The relationship between properties of MARs and structures of target compound effects the law of adsorption selection, and the investigation of this relationship is the key problem of theoretical research on separation and adsorption. Moreover, the ultimate purpose of theoretical research on MARs is the establishment and evaluation of adsorption model which could explain the adsorption process objective with a wide range of applications. At last, some suggestions for considering multi-layer adsorption process, adsorption and desorption rates, features of adsorption solution, and physical parameters of MARs into the derivation of model are put forward. Contents 1 Introduction
2 Adsorption isotherms
3 Adsorption kinetcis
4 Interaction forces of adsorption
5 Adsorption model
6 Outlook
Key words: macroporous adsorption resins, adsorption mechanism, adsorption model

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