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Gelation of Polyacrylonitrile Solution

Wan Ajun*, Tan Lianjiang   

  1. School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
  • Received: Revised: Online: Published:
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Polyacrylonitrile (PAN) is one of the most widely used polymers. PAN solutions using suitable solvents are the precursors for fabrication of PAN fibers, osmotic membranes and other PAN-related materials. The physical and chemical properties of PAN solutions have great effect on the performance of the resultant materials. In this article, the gelation characteristics of polymer solution and the characteristics of polymer gels as well as the characteristics of PAN and PAN gels are introduced. Suitable characterization methods for the gelation of PAN solutions are proposed according to the properties of concentrated polymer solution systems. The recent research findings and latest progress of gelation of PAN solutions are summarized in the following respects: influences of concentration and temperature on gelation behavior of PAN solutions, influences of aging and non-solvent on gelation behavior of PAN solutions, thermoreversibility of gelation of PAN solutions, fractal characteristics of gelation of PAN solutions, and crosslinking mechanism of polyacrylonitrile gels. The gelation behavior of PAN solutions and the state of PAN gels have been found to be greatly affected by external environment and the composition of the gels. Finally the research prospect of the gelation of PAN solutions and PAN gels is expected. Contents
1 Introduction
2 Gelation of polymer solutions
3 Gelation behavior of polyacrylonitrile solutions
3.1 Influences of concentration and temperature on gelation behavior of polyacrylonitrile solutions
3.2 Influences of aging and non-solvent on gelation behavior of polyacrylonitrile solutions
3.3 Thermoreversibility of gelation of polyacrylonitrile solutions
3.4 Fractal characteristics of gelation of polyacrylonitrile solutions
3.5 Crosslinking mechanism of polyacrylonitrile gels
4 Conclusions and outlook
Key words: polyacrylonitrile, solution, gelation

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Abstract

Gelation of Polyacrylonitrile Solution