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Progress in Chemistry 2009, Vol. 21 Issue (09): 1742-1749 Previous Articles   Next Articles

• Review •

Gold Nanoparticles Supported on Mesoporous Silica and Their Catalytic Applications

Li Li1 |Ji Weijie1,* |Au Chek-Tong2,*   

  1. (1. Key Laboratory of Mesoscopic Chemistry, MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing210093, China; 2. Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong, China)
  • Received: Revised: Online: Published:
  • Contact: Ji Weijie;Au Chek-Tong E-mail:jiwj@nju.edu.cn; pctau@hkbu.edu.hk
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Gold catalysis is becoming the frontier research field in catalysis chemistry. The present article intends to review recent progress in the fabrication of Au nanoparticles supported on mesoporous silica (MCM-41, MCM-48, and particularly SBA-15) and their catalytic applications in low-temperature CO oxidation, cyclohexene hydrogenation, and cyclohexane oxidation. The latest knowledge on the factors determining the characteristics and catalytic performance of Au nanoparticles, such as the type and surface property of support, the size, dispersion, location, and stability of Au nanoparticles, has been summarized and the related discussion is given.

Contents
1 Introduction
2 Au nanoparticles dispersed on mesoporous SiO2 and their applications
2.1 Catalysts prepared by deposition-precipitation
2.2 Catalysts prepared by hydrothermal synthesis
2.3 Catalysts prepared with surface modifications
3 Summary and perspective

Key words: Au catalyst, nanoparticles, mesoporous structure, silica

CLC Number: 

[ 1 ] 　Haruta M, Daté M. Appl . Catal . A: Gen. , 2001 , 222 (1/2) :427 —437
[ 2 ] 　Hayashi T, Tanaka K, Haruta M. J . Catal . , 1998 , 178 ( 2) :566 —575
[ 3 ] 　Haruta M, Tsubota S , Kobayashi T, et al . J . Catal . , 1993 , 144(1) : 175 —192
[ 4 ] 　Salama TM, Ohmishi R , Ichikawa M, et al . J . Catal . , 1996 , 162(2) : 169 —178
[ 5 ] 　Link S , Mohamed MB , El-Sayed MA. J . Phys. Chem. B , 1999 ,103 (16) : 3073 —3077
[ 6 ] 　Bond G C. Catal . Today , 2002 , 72 (1P2) : 5 —9
[ 7 ] 　Prati L , Rossi M. J . Catal . , 1998 , 176 (2) : 552 —560
[ 8 ] 　Carrettin S , McMorn P , Hutchings GJ , et al . Chem. Commun. ,2002 , 2 (7) : 696 —697
[ 9 ] 　Wallace W T, Min B K, Goodman D W. J . Mol . Catal . A , 2005 ,228 (1/2) : 3 —10
[10 ] 　Schubert MM, Hackenberg S , Muhler M, et al . J . Catal . , 2001 ,197 (1) : 113 —122
[11 ] 　Chen M S , Goodman D W. Catal . Today , 2006 , 111 (1-2) : 22 —33
[12 ] 　Lee S J , Gavriilidis A. J . Catal . , 2002 , 206 (2) : 305 —313
[13 ] 　Wolf A , Schüth F. Appl . Catal . A: Gen. , 2002 , 226 (1P2) : 1 —13
[14 ] 　Sermon P A , SivalingamJ . Colloids Surf . , 1992 , 63 (1P2) : 59 —65
[15 ] 　Tsubota S , Cunningham D A H , Haruta M, et al . Stud. Surf . Sci .Catal . , 1995 , 91 : 227 —235
[16 ] 　Bandyopadhyay M, Korsak O , Gies H , et al . Micropor. Mesopor.Mater. , 2006 , 89 (1P3) : 158 —163
[17 ] 　Bandyopadhyay M, Birkner A , Gies H , et al . Chem. Mater. ,2005 , 17 (15) : 3820 —3829
[18 ] 　Chiang C W, Wang A Q , Mou C Y. Catal . Today , 2006 , 117 (1/3) : 220 —227
[19 ] 　LüGM, Zhao R , Qi Y X, et al . Catal . Lett . , 2004 , 97 (3/4) :115 —118
[20 ] 　Zhao R , Ji D , Suo J S. Chem. Commun. , 2004 , 904 —905
[21 ] 　Akolekar D B , Bhargava S K. J . Mol . Catal . A: Chem. , 2005 ,236 (1/2) : 77 —86
[22 ] 　Zhu H G, Liang C D , Dai S , et al . J . Phys. Chem. B , 2006 , 110(22) : 10842 —10848
[23 ] 　Yang C M, Liu P H , Chao KJ , et al . Chem. Mater. , 2003 , 15(1) : 275 —280
[24 ] 　Yang C M, Kalwei M, Schüth F , et al . Appl . Catal . A: Gen. ,2003 , 254 (2) : 289 —296
[25 ] 　Zhou L H , Hu J , Liu HL , et al . Chin. J . Chem. Eng. , 2007 , 15(4) : 507 —511
[26 ] 　Chao K J , Cheng M H , Ho Y F. Catal . Today , 2004 , 97 (1) :49 —53
[27 ] 　Liu P H , Chang Y P , Chao KJ , et al . Mater. Sci . Eng. C , 2006 ,26 (5/7) : 1017 —1022
[28 ] 　Mukherjee P , Sastry M, Kumar R. Phys. Chem. Commun. , 2000 ,3 (4) : 15 —17
[29 ] 　Xu Y, Langford C H. J . Phys. Chem. B , 1997 , 101 (16) : 3115 —3121
[30 ] 　Hirai T, Okubo H , Komasawa I. J . Phys. Chem. B , 1999 , 103(21) : 4228 —4230
[31 ] 　Guari Y, Thieuleux C , Chaudret B , et al . Chem. Commun. , 2001 ,1374 —1375
[32 ] 　Zhu H G, Dai S , Overbury S H. Langmuir , 2003 , 19 (9) : 3974 —3980
[33 ] 　Ghosh A , Sastry M, Kumar R , et al . Micropor. Mesopor. Mater. ,2003 , 58 (3) : 201 —211
[34 ] 　Chi Y S , Lin H , Mou C Y. Appl . Catal . A: Gen. , 2005 , 284 (1/2) : 199 —206
[35 ] 　Hu J C , Suchopar A , Richards R , et al . Catal . Today , 2007 , 122(3/4) : 277 —283
[36 ] 　Gu J , Fan W, Okubo T, et al . J . Solid State Chem. , 2008 , 181(4) : 957 —963
[37 ] 　Chiang C W, Wang A Q , Mou C Y, et al . J . Phys. Chem. B ,2005 , 109 (38) : 18042 —18047
[38 ] 　Chiang C W, Wang A Q , Mou C Y. Catal . Today , 2006 , 117 (1/3) : 220 —227
[39 ] 　Yan W F , Petbov V , Dai S , et al . Catal . Commun. , 2005 , 6 (6) :404 —408
[40 ] 　Ruszel M, Grzybowska B , Laniecki M, et al . Catal . Commun. ,2007 , 8 (8) : 1284 —1286
[41 ] 　Sacaliuc E , Weckhuysen B M, Nijhuis TA , et al . J . Catal . , 2007 ,248 (2) : 235 —248
[42 ] 　Xu X Y, Li J J , Hao Z P , et al . Mater. Res. Bull . , 2006 , 41 (2) :406 —413
[43 ] 　桂建舟(Gui J Z) , 刘丹(Liu D) , 邱宝军(Qiu B J ) 等. 应用化工(Applied Chemical Industry) , 2006 , 35 (3) : 161 —163
[44 ] 　Zhu K K, Hu J C , Richards R. Catal . Lett . , 2005 , 100 (3/4) :195 —199
[45 ] 　Li L , Ji W J , van der Knaap T, et al . Kyoto 2008 ICC 14 Pre-Symposium , Kyoto , 2008. OB2106
[46 ] 　Li L , Ji WJ , Au C T, et al . Catal . Lett . , 2009 , 129 (3/4) : 303 —311
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