中文
Earlier issues
Announcement
More
Progress in Chemistry 2011, Vol. 23 Issue (5): 874-879 Previous Articles   Next Articles

• Review •

Solid-Phase Photocatalytic Degradation of Waste Plastics

Yang Changjun1, Peng Tianyou1, Deng Kejian2, Zan Ling1   

  1. 1. College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 43007;
    2. Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission & Ministry of Education, Hubei Province, South-Central University for Nationalities, Wuhan 430074, China
  • Received: Revised: Online: Published:
PDF ( 2115 ) Cited
Export

EndNote

Ris

BibTeX

White pollution has become a global environmental issue in recent years. Composite plastics embedding photocatalysts into ploymer matrix has excellent photocatalytic degradation activity. It could be degraded effectively in ambient air under sunlight exposure. So it is an eco-friendly disposal of polymer wastes, and provides a promising way to solve white pollution. In this paper, the latest research progress in solid-phase photocatalytic degradation of waste plastics is reviewed. The solid-phase photocatalytic activity of TiO2, ZnO, α-FeOOH and H3PW12O40, as well as the photocatalytic degradation mechanism of various composite plastics are introduced. Many new methods have been used to enhance the solid-phase photocatalytic degradation activity of composite plastics and the utilization efficiency of sunlight. For example, surface modifying photocatalyst by branched macromolecule is used to improve the dispersion of photocatalyst in polymer matrix, modifying photocatalyst by metal ion doping or dye sensitization is used to broaden the region of photoresponse and enhance the visible light activity of photocatalyst. At last,the potential application prospects for photodegradable composite plastics in the field of waste plastic treatment is discussed.

Key words: solid-phase photocatalytic degradation, photocatalysts, photodegradable plastics, polymer composite plastics

CLC Number: 

[1] 法文君(Fa W J), 昝菱(Zan L), 龚楚清(Gong C Q), 钟家柽(Zhong J C). 化学进展(Progress in Chemistry), 2008, 20(1): 19-25
[2] 高涛(Gao T), 章煜君(Zhang Y J), 潘立(Pan L). 机电工程(Mechanical & Electrical Engineering Magazine), 2009, 26(6): 5-8
[3] Valavanidis A, Iliopoulos N, Gotsis G, Fiotakis K. J. Hazard. Mater., 2008, 156: 277-284
[4] Yasuhara A, Katami T, Shibamoto T. Bull. Environ. Contam. Toxicol., 2005, 74: 899-903
[5] Lemieux P M, Lutes C C, Santoianni D A. Prog. Energy Combust. Sci., 2004, 30: 1-32
[6] Hoffmann M R, Martin S T, Choi W, Bahnemannt D W. Chem. Rev., 1995, 95: 69-96
[7] Yu J G, Su Y R, Cheng B. Adv. Funct. Mater., 2007, 17: 1984-1990
[8] Yang D J, Liu H W, Zheng Z F, Yuan Y, Zhao J C, Waclawik E R, Ke X B, Zhu H Y. J. Am. Chem. Soc., 2009, 131: 17885-17893
[9] Thompson T L, Yates J T Jr. Chem. Rev., 2006, 106: 4428-4453
[10] Hidaka H, Suzuki Y, Nohara K, Horikoshi S, Hisamatsu Y, Pelizzetti E, Serpone N. J. Polym. Sci. Part A: Polym. Chem., 1996, 34: 1311-1316
[11] Horikoshi S, Serpone N, Hisamatsu Y, Hidaka H. Environ. Sci. Technol., 1998, 32: 4010-4016
[12] Cho S, Choi W. J. Photochem. Photobiol. A: Chemistry, 2001, 143: 221-228
[13] Shang J, Chai M, Zhu Y F. J. Solid State Chem., 2003, 174: 104-110
[14] Allen N S, Edge M, Ortega A, Sandoval G, Liauw C M, Verran J, Stratton J, McIntyre R B. Polym. Degrad. Stab., 2004, 85: 927-946
[15] Zhao X, Li Z W, Chen Y, Shi L Y, Zhu Y F. J. Mol. Catal. A: Chem., 2007, 268: 101-106
[16] Jin C, Christensen P A, Egerton T A, Lawson E J, White J R. Polym. Degrad. Stab., 2006, 91: 1086-1096
[17] Fa W J, Zan L, Gong C Q, Zhong J C, Deng K J. Appl. Catal., B: Environmental, 2007, 79: 216-223
[18] Zan L, Fa W J, Wang S L. Environ. Sci. Technol., 2006, 40: 1681-1685
[19] Zan L, Tian L H, Liu Z S, Peng Z H. Appl. Catal. A: General, 2004, 264: 237-242
[20] Zan L, Wang S L, Fa W J, Hu Y H, Tian L H, Deng K J. Polymer, 2006, 47: 8155-8162
[21] 田丽红(Tian L H), 王娟(Wang J), 昝菱(Zan L). 化学与生物工程(Chemistry & Bioengineering), 2006, 23(9): 13-14
[22] 法文君(Fa W J), 昝菱(Zan L), 胡严鹤(Hu Y H), 陈俊桥(Chen J Q). 武汉大学学报(理学版)(J. Wuhan Univ.: Nat. Sci. Ed. ), 2005, 51(4): 402-406
[23] Kim S H, Kwak S, Suzuki T. Polymer, 2006, 47: 3005-3016
[24] 朱焕扬(Zhu H Y), 杨斌(Yang B), 张剑平(Zhang J P), 朱惟德(Zhu W D), 施利毅(Shi L Y). 功能材料(Journal of Functional Materials), 2007, 38(3): 462-468
[25] Kemp T J, McIntyre R A. Polym. Degrad. Stab., 2006, 91: 3020-3025
[26] Kemp T J, McIntyre R A. Polym. Degrad. Stab., 2006, 91: 3010-3019
[27] Kemp T J, McIntyre R A. Polym. Degrad. Stab., 2006, 91: 165-194
[28] 李凤仪(Li F Y), 熊裕华(Xiong Y H). 中国稀土学报(Journal of the Chinese Rare Earth Society), 2005, 23(4): 444-448
[29] 韩玉琦(Han Y Q), 常希俊(Chang X J), 敏世雄(Min S X), 王芳(Wang F), 冯雷(Feng L), 刘玉凤(Liu Y F). 环境工程(Environmental Engineering), 2009, 27: 364-366
[30] 熊裕华(Xiong Y H), 李凤仪(Li F Y). 物理化学学报(Acta Phys. Chim. Sin. ), 2005, 21(6): 607-611
[31] Shang J, Chai M, Zhu Y F. Environ. Sci. Technol., 2003, 37: 4494-4499
[32] Zhao X, Li Z W, Chen Y, Shi L Y, Zhu Y F. Appl. Surf. Sci., 2008, 254: 1825-1829
[33] 陈怡(Chen Y), 袁帅(Yuan S), 施利毅(Shi L Y), 朱焕扬(Zhu H Y), 张剑平(Zhang J P). 高等学校化学学报(Chemical Journal of Chinese Universities), 2008, 29(3): 554-558
[34] Akyol A, Yatmaz H C, Bayramoglu M. Appl. Catal. B: Environmental, 2004, 54: 19-24
[35] Comparelli R, Fanizza E, Curri M L, Cozzoli P D, Mascolo G, Agostiano A. Appl. Catal. B: Environmental, 2005, 60: 1-11
[36] Jing L Q, Wang D J, Wang B Q, Li S D, Xin B F, Fu H G, Sun J Z. J. Mol. Catal. A: Chem., 2006, 244: 193-200
[37] Akyol A, Bayramoglu M. J. Hazard. Mater., 2010, 180: 466-473
[38] Kong J Z, Li A D, Li X Y, Zhai H F, Zhang W Q, Gong Y P, Li H, Wu D. J. Solid State Chem., 2010, 183: 1359-1364
[39] Sil D, Chakrabarti S. Sol. Energy, 2010, 84: 476-485
[40] Chakrabarti S, Chaudhuri B, Bhattacharjee S, Das P, Dutta B K. J. Hazard. Mater., 2008, 154: 230-236
[41] Bandyopadhyay A, Basak G C. Mater. Sci. Technol., 2007, 23(3): 307-314
[42] Li F B, Li X Z, Liu C S, Liu T X. J. Hazard. Mater., 2007, 149: 199-207
[43] Cao S W, Zhu Y J. J. Phys. Chem. C, 2008, 112: 6253-6257
[44] Li L L, Chu Y, Liu Y, Dong L H. J. Phys. Chem. C, 2007, 111: 2123-2127
[45] Lu M C. Chemosphere, 2000, 40: 125-130
[46] Zhang Z, Hossain M F, Takahashi T. Appl. Catal. B: Environmental, 2010, 95: 423-429
[47] Liu G L, Zhu D W, Liao S J, Ren L Y, Cui J Z, Zhou W B. J. Hazard. Mater., 2009, 172: 1424-1429
[48] Liu G L, Zhu D W, Zhou W B, Liao S J, Cui J Z, Wu K, Hamilton D. Appl. Surf. Sci., 2010, 256: 2546-2551
[49] Antonaraki S, Androulaki E, Dimotikali D, Hiskia A, Papaconstantinou E. J. Photochem. Photobiol. A: Chemistry, 2002, 148: 191-197
[50] Kormali P, Dimoticali D, Tsipi D, Hiskia A, Papaconstantinou E. Appl. Catal. B: Environmental, 2004, 48: 175-183
[51] Hu M Q, Xu Y M. Chemosphere, 2004, 54: 431-434
[52] Zhang K H, Cao W L, Zhang J C. Appl. Catal. A: General, 2004, 276: 67-73
[53] Zhang K H, Zhang J C, Cao W L. Chin. Chem. Lett., 2005, 16(5): 667-670l Materials), 2007, 38(3): 462-468

[25] Kemp T J, McIntyre R A. Polym. Degrad. Stab., 2006, 91: 3020-3025

[26] Kemp T J, McIntyre R A. Polym. Degrad. Stab., 2006, 91: 3010-3019

[27] Kemp T J, McIntyre R A. Polym. Degrad. Stab., 2006, 91: 165-194

[28] 李凤仪(Li F Y), 熊裕华(Xiong Y H). 中国稀土学报(Journal of the Chinese Rare Earth Society), 2005, 23(4): 444-448

[29] 韩玉琦(Han Y Q), 常希俊(Chang X J), 敏世雄(Min S X), 王芳(Wang F), 冯雷(Feng L), 刘玉凤(Liu Y F). 环境工程(Environmental Engineering), 2009, 27: 364-366

[30] 熊裕华(Xiong Y H), 李凤仪(Li F Y). 物理化学学报(Acta Phys. Chim. Sin. ), 2005, 21(6): 607-611

[31] Shang J, Chai M, Zhu Y F. Environ. Sci. Technol., 2003, 37: 4494-4499

[32] Zhao X, Li Z W, Chen Y, Shi L Y, Zhu Y F. Appl. Surf. Sci., 2008, 254: 1825-1829

[33] 陈怡(Chen Y), 袁帅(Yuan S), 施利毅(Shi L Y), 朱焕扬(Zhu H Y), 张剑平(Zhang J P). 高等学校化学学报(Chemical Journal of Chinese Universities), 2008, 29(3): 554-558

[34] Akyol A, Yatmaz H C, Bayramoglu M. Appl. Catal. B: Environmental, 2004, 54: 19-24

[35] Comparelli R, Fanizza E, Curri M L, Cozzoli P D, Mascolo G, Agostiano A. Appl. Catal. B: Environmental, 2005, 60: 1-11

[36] Jing L Q, Wang D J, Wang B Q, Li S D, Xin B F, Fu H G, Sun J Z. J. Mol. Catal. A: Chem., 2006, 244: 193-200

[37] Akyol A, Bayramoglu M. J. Hazard. Mater., 2010, 180: 466-473

[38] Kong J Z, Li A D, Li X Y, Zhai H F, Zhang W Q, Gong Y P, Li H, Wu D. J. Solid State Chem., 2010, 183: 1359-1364

[39] Sil D, Chakrabarti S. Sol. Energy, 2010, 84: 476-485

[40] Chakrabarti S, Chaudhuri B, Bhattacharjee S, Das P, Dutta B K. J. Hazard. Mater., 2008, 154: 230-236

[41] Bandyopadhyay A, Basak G C. Mater. Sci. Technol., 2007, 23(3): 307-314

[42] Li F B, Li X Z, Liu C S, Liu T X. J. Hazard. Mater., 2007, 149: 199-207

[43] Cao S W, Zhu Y J. J. Phys. Chem. C, 2008, 112: 6253-6257

[44] Li L L, Chu Y, Liu Y, Dong L H. J. Phys. Chem. C, 2007, 111: 2123-2127

[45] Lu M C. Chemosphere, 2000, 40: 125-130

[46] Zhang Z, Hossain M F, Takahashi T. Appl. Catal. B: Environmental, 2010, 95: 423-429

[47] Liu G L, Zhu D W, Liao S J, Ren L Y, Cui J Z, Zhou W B. J. Hazard. Mater., 2009, 172: 1424-1429

[48] Liu G L, Zhu D W, Zhou W B, Liao S J, Cui J Z, Wu K, Hamilton D. Appl. Surf. Sci., 2010, 256: 2546-2551

[49] Antonaraki S, Androulaki E, Dimotikali D, Hiskia A, Papaconstantinou E. J. Photochem. Photobiol. A: Chemistry, 2002, 148: 191-197

[50] Kormali P, Dimoticali D, Tsipi D, Hiskia A, Papaconstantinou E. Appl. Catal. B: Environmental, 2004, 48: 175-183

[51] Hu M Q, Xu Y M. Chemosphere, 2004, 54: 431-434

[52] Zhang K H, Cao W L, Zhang J C. Appl. Catal. A: General, 2004, 276: 67-73

[53] Zhang K H, Zhang J C, Cao W L. Chin. Chem. Lett., 2005, 16(5): 667-670

 
[1] Zhang Xia, Fan Jing. Carbon Materials Modified Bismuth Based Photocatalysts and Their Applications [J]. Progress in Chemistry, 2016, 28(4): 438-449.
[2] Zhang Xiaodong, Yang Yang, Li Hongxin, Zou Xuejun, Wang Yuxin. Non-TiO2 Photocatalysts Used for Degradation of Gaseous VOCs [J]. Progress in Chemistry, 2016, 28(10): 1550-1559.
[3] Jin Chao, Qin Yao, Yang Jinhu. Novel Non-TiO2 Semiconductor Photocatalysts [J]. Progress in Chemistry, 2014, 26(0203): 225-233.
[4] Duan Fang, Zhang Qin, Wei Qufu, Shi Dongjian, Chen Mingqing. Control of Photocatalytic Property of Bismuth-Based Semiconductor Photocatalysts [J]. Progress in Chemistry, 2014, 26(01): 30-40.
[5] Fa Wenjun|Zan Ling**|Gong Chuqing|Zhong Jiacheng. Solid-phase Photocatalytic Degradation of Plastic with TiO2 as Photocatalyst [J]. Progress in Chemistry, 2008, 20(01): 19-25.
[6] . Progress of Semiconductor Photocatalysts Under Visible Light Irradiation [J]. Progress in Chemistry, 2005, 17(02): 242-247.
[7] . Recent Progress in Titania Photocatalyst Operating Under Visible Light [J]. Progress in Chemistry, 2005, 17(01): 8-14.