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Progress in Chemistry 2010, Vol. 22 Issue (10): 1921-1928 Previous Articles   Next Articles

• Review •

Functional Ionic liquids/Porous Silica Compostes

Chen Chuandong1  Zhai Shangru1**   Zhai Bin1**  Wu Hejuan1 An Qingda1  Sun Yuhan2   

  1. (1. Faculty of Chemical Engineering and Material, Dalian Polytechnic University, Dalian 116034, China; 2. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, the Chinese Academy of Sciences, Taiyuan 030001, Shanxi)
  • Received: Revised: Online: Published:
  • Contact: Zhai Shangru E-mail:zhai_shangru@yahoo.com.cn
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The popularity of ionic liquids has significantly increased over the last decade. Among reported studies on ionic liquids, the preparation and application of supported ionic liquid are of great importance due to the combination of both advabntages of  ionic liquids and those of hetergeneous support materials. The viability of this concept has recently confirmed by many studies which have successfully supported various ionic liquids on the surface of porous silicas and explored their potential applications in various fields. The  preparation of these compostes was mainly achieved by using two kinds of silica-based materals,namely  xerogels and ordered mesostructures,via two different immobilization approaches of covalent  attachment and simple deposit. Utilizing and application of ionic liquids/porous silicas associated with dual advantages is an attractive research direction, recently. In this respect, the recent research progress on the objective composites are summarized on the basis of the effectiveness of the synthesis pathways. Meanwhile, the potential applications are also prospected.

Contents
1 Introduction
2 Preparation and applications of supported ionic liquids/silica-xerogel catalysts
3 Preparation and application of supported ionic liquids/OMS(ordered mesoporous silicas) catalytic materials
3.1 Directly used as catalysts in various reactions
3.2 Supports for active metal nanoparticles or metal complex
4 Conclusions

 

Key words: ionic liquids, mesoporous, silicas, synthesis, application

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