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Progress in Chemistry 2019, Vol. 31 Issue (4): 597-612 DOI: 10.7536/PC180909 Previous Articles   Next Articles

Solar Spectrum Selective Absorbing Coatings

Ningning Cao1, Songtao Lu1, Rui Yao1, Huimin Li1, Wei Qin2, Xiaohong Wu1,**()   

  1. 1. MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China
    2. National Defense Science and Technology Key Lab for Space Materials Behavior and Evaluation, School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
  • Received: Online: Published:
  • Contact: Xiaohong Wu
  • About author:
    ** E-mail:
  • Supported by:
    National Natural Science Foundation of China(51671074); National Natural Science Foundation of China(51572060); National Natural Science Foundation of China(51502062); China Postdoctoral Science Foundation Funded Project(2016M590279)
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Solar energy, as the most important renewable energy source, has many advantages such as abundant reserves, wide distribution, cleanliness and safety. Therefore, the research on solar energy utilization technologies has important implications of enriching energy structure, reducing environmental pollution, and optimizing resource allocation. And as a note, the photo-thermal conversion is the simplest and most efficient way to achieve direct utilization of solar energy. This paper briefly introduces the significance, advantages and disadvantages of solar energy, and comprehensively analyzes the basic types, absorption mechanisms and the latest research results of selective absorbing coatings for indirect solar collectors. Finally, the existing problems, challenges and prospects for the development of spectrally selective absorbing coatings used for solar collectors are also commented.

Key words: solar energy, photo-thermal conversion, solar collectors, selective absorbing coatings
Fig. 1 Schematic of(a) surface coating based and(b) direct absorption based solar collectors
Fig. 2 Structural diagram of the cermet absorbing coating
Fig. 3 Sketch of the double cermet coating
Fig. 4 Schematic of the one-step preparation of C-Cu-TiO2 solar absorber coating[15]
Fig. 5 (a) Schematic of the semiconductor-metal tandems, absorption mechanism of(b) semiconductor and(c) semiconductor-metal tandem material
Fig. 6 Schematic of multi-layered optical interference absorber coating:(a) type D/A/D and(b) type AR/D/A/D/A
Table 1 Absorptance(α) and thermal emittance(εT) of layer-added solar absorber with different construct[77]
Structural Composition α εT
L1 Mo 0.433 0.054
L2 Mo/Si3N4 0.703 0.061
L4 Mo/Si3N4/Mo/Si3N4 0.909 0.113
L5 Mo/Si3N4/Mo/Si3N4/SiO2 0.933 0.116
L7 Mo/Si3N4/Mo/Si3N4/Mo/Si3N4/SiO2 0.964 0.163
Table 2 Thickness for each layer, absorptance(α) and thermal emittance(εT) of colored solar absorber coatings with structure Ti/SiO2/Ti/TiO2/SiO2[77]
d [Ti/SiO2/Ti/TiO2/SiO2](nm) α εT
Purple 18/55/21/30/85 0.956 0.085
Blue 24/69/21/26/92 0.963 0.081
Bluish-green 23/84/22/43/87 0.957 0.086
Yellowish-green 24/64/30/35/95 0.951 0.078
Orange-yellow 20/41/21/37/72 0.950 0.089
Fig. 7 Schematic of textured surface absorber coating
Fig. 8 (a) Schematic of TiAlN absorber coating with nanophotonic structure,(b) Absorption spectra of bare Cu substrate, plane Cu/TiAlN and nanostructured Cu/TiAlN coatings[116]. Copyright: Royal Society of Chemistry.
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