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化学进展 2007, Vol. 19 Issue (0203): 283-291 前一篇   后一篇

• 综述与评论 •

环钯化合物在Heck反应中的应用研究

史荣会1;刘 晔2;刘 蒲1*;王向宇1   

  1. 1.郑州大学化学系 郑州 450052；

    2. 上海市绿色化学与化工过程绿色化重点验室 华东师范大学化学系，上海200062

  • 收稿日期:2006-03-27 修回日期:2006-05-25 出版日期:2007-03-24 发布日期:2007-03-24
  • 通讯作者: 刘蒲
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导出 被引次数 ( 20 | 2 )

Application of Palladacycles in Heck Reactions

Shi Ronghui1;Liu Ye2;Liu Pu1*; Wang Xiangyu1   

  1. 1.Department of Chemistry, Zhengzhou University, Zhengzhou 450052,China; 2.Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062,China
  • Received:2006-03-27 Revised:2006-05-25 Online:2007-03-24 Published:2007-03-24
  • Contact: Liu Pu
钯催化交叉偶联反应在化学工业、合成天然产物及生物活性物质的合成中有着广泛应用。催化剂体系是交叉偶联反应研究的核心。环钯化合物作为结构简单、性能稳定的高活性、高选择性交叉偶联反应催化剂引起极大关注，不断有新的环钯化合物被合成及其催化性能被研究。因此本文对环钯化合物的合成方法以及在Heck反应中的应用作了综述。
关键词： 环钯化合物, Heck反应, 催化性能
Palladium-catalyzed cross-coupling reactions have been widely applied in chemical industry, synthesis of natural products and biological active substance. The catalytic system is the key of cross-coupling reaction. Palladacycles, which have simple structures, stable properties and show high activity and selectivity as catalysts in cross-coupling reactions, have attracted great attention, some new palladacycles are synthesized and their catalytic activities are studied in succession. In this paper, the synthesis methods and applications in the Heck reactions are reviewed.
Key words: palladacycles, Heck reaction, catalytic activity

中图分类号: 

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