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化学进展 2016, Vol. 28 Issue (7): 1006-1015 DOI: 10.7536/PC160401 前一篇   后一篇

• 综述与评论 •

共价有机框架材料催化剂

付先彪1, 喻桂朋1,2*   

  1. 1. 中南大学 化学化工学院 长沙 410083;
    2. 大连理工大学 精细化工国家重点实验室 大连 116012
  • 收稿日期:2016-04-01 修回日期:2016-04-01 出版日期:2016-07-15 发布日期:2016-05-17
  • 通讯作者: 喻桂朋 E-mail:gilbertyu@csu.edu.cn
  • 基金资助:
    国家自然科学基金项目（No.21204103,21376272）和湖南省自然科学-株洲市联合基金项目（No.20155015）资助
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导出 被引次数 ( 2 | 4 )

Covalent Organic Frameworks Catalysts

Fu Xianbiao1, Yu Guipeng1,2*   

  1. 1. College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;
    2. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China
  • Received:2016-04-01 Revised:2016-04-01 Online:2016-07-15 Published:2016-05-17
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No.21204103,21376272),and the Joint Funds of Hunan Provincial Natural Science Foundation and Zhuzhou Municipal Government of China (No.2015JJ5015).
共价有机框架材料（covalent organic frameworks, COF）是功能材料领域研究的热点之一。COF具有孔道结构高度有序、孔径可调、比表面积较大、合成方法多样和易于功能化修饰等优点，是一类新兴的多相催化剂。目前，COF催化剂主要设计思路是：基于“自下而上”策略将非金属催化活性中心嵌入材料骨架来构筑本征型COF催化剂，或者以COF为载体，通过后修饰方式负载金属颗粒或离子构建多相催化剂。鉴于COF以上优势，预计COF催化剂在多相催化和手性催化领域中的应用也将取得更大的进展。本文综述了COF催化剂的合成和功能化策略，并展望了COF在多相催化领域中的应用前景。
关键词： 共价有机框架材料, "自下而上"策略, 多相催化, 多孔聚合物
Covalent organic frameworks (COF) arise as the new frontier among the enormous research efforts in functional materials. Due to their well-defined channel structure, tunable porosity, larger surface area, vast synthetic diversity and facile functionalization at the molecular level, COF has emerged as a matrix for heterogeneous catalysts. Such catalysts are generally constructed via the "bottom-up" strategies from building blocks. Utilizing a simple post- modification strategy, COF catalysts are prepared by loading metal particles or ions into the pores or interfaces. Benefiting from its structural superiority, COF catalysts with excellent catalytic activity will also make a great achievement. Here, this review focuses on recent advances of COF-functional catalysts, by briefly summarizing their synthetic strategies, targeted functionalization, and their perspectives in heterogeneous catalysis.

Contents
1 Introduction
2 Pd catalytic coupling reaction
2.1 Suzuki reaction
2.2 Sonogashira reaction
2.3 Heck reaction
3 Knoevenagel condensation
4 Redox reaction
5 Diels-Alder reaction
6 Michael addition
7 Solid acid catalysis reaction
8 Photocatalytic hydrogen production
9 Conclusion and outlook

Key words: covalent organic frameworks, bottom-up strategy, heterogeneous catalysis, porous polymers

中图分类号: 

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摘要

共价有机框架材料催化剂