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化学进展 2010, Vol. 22 Issue (0203): 284-290 前一篇   后一篇

• 综述与评论 •

超疏水模型及其机理*

柯清平;李广录;郝天歌;何涛**;李雪梅**   

  1. (南京工业大学材料化学工程国家重点实验室 南京 210009)
  • 收稿日期:2009-04-14 修回日期:2009-05-08 出版日期:2010-03-24 发布日期:2010-03-18
  • 通讯作者: 何涛;李雪梅 E-mail:taohe@njut.edu.cn;xuemeili@njut.edu.cn
  • 基金资助:

    高强度、高稳定超疏水涂层材料的制备

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Superhydrophobicity: Theoretical Models and Mechanism

Ke Qingping;  Li Guanglu;  Hao Tiange;  He Tao**;  Li Xuemei**   

  1. (State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China)
  • Received:2009-04-14 Revised:2009-05-08 Online:2010-03-24 Published:2010-03-18
  • Contact: He Tao; Li Xuemei E-mail:taohe@njut.edu.cn;xuemeili@njut.edu.cn

超疏水表面是指具有非常高的水接触角，且水滴能轻易流动的表面。由于超疏水表面具有自清洁、防黏附、防雪粘等功能，在许多领域中用途广泛，有关超疏水表面制备和理论研究成为了研究的热点。特别是有关超疏水表面的理论，由于涉及表面结构的优化设计，更受到了广泛的关注。本文综述了近年来超疏水理论的新进展，重点归纳了一些具有代表性的理论，如经典的Wenzel理论和Cassie理论、过渡态的产生及如何避免过渡态的问题、接触线理论、多尺度效应等等，对各个理论的优缺点进行了系统地比较和评价，另外，对一些热点关注问题也进行了综述，并对超疏水理论的未来发展方向进行了展望。

关键词： 超疏水理论, 过渡态, 多尺度, 润湿

High water contact angles and low contact angle hysteresis are two key characteristics of superhydrophobic surfaces. Because of the self-cleaning, anti-snow sticking properties, superhydrophobic surfaces have potential applications in many fields. Abundant works have been reported in the last decade both on their preparation and theories. The theories have drawn special attention because of its relevance to the optimization of designing superpydrophobic surfaces. In this review, we summary and compare the classic theories on superhydrophobic surfaces, both on their advantages and shortcomings. New developments in the theories are elaborated and evaluated with focus on the root cause of transition state and how to avoid, contact line density theory, multi-scale effects, etc. Finally, an outlook is given on the development of superhydrophobic theories.

Contents
1 Introduction
2 Theories on superhydrophobicity
2.1 Transition state
2.2 Contact line
2.3 Multi-scale effects
2.4 New issues
3 Conclusion and outlook

Key words: superhydrophobic theory, transition state, multi-scale, wetting

中图分类号: 

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摘要

超疏水模型及其机理*