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化学进展 2017, Vol. 29 Issue (2/3): 231-240 DOI: 10.7536/PC161012 前一篇   后一篇

• 综述 •

液态锂资源提锂的吸附材料及性能

张文1*, 牟英炘1, 赵颂1, 解利昕1, 王宇新1, 陈靖2   

  1. 1. 天津大学化工学院 天津市膜科学与海水淡化重点实验室 化学工程联合国家重点实验室 天津 300350;
    2. 清华大学核能与新能源技术研究院 先进核能技术协同创新中心 北京 102201
  • 收稿日期:2016-10-11 修回日期:2016-12-16 出版日期:2017-02-15 发布日期:2017-04-10
  • 通讯作者: 张文 E-mail:zhang_wen@tju.edu.cn.
  • 基金资助:
    国家自然科学基金项目（No.U1430234），天津市自然科学基金项目（No.16JCQNJC06000）和国家科技支撑计划项目（No.2015BAB10B00）资助
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Adsorption Materials for Lithium Ion from Brine Resources and Their Performances

Wen Zhang1*, Yingxin Mou1, Song Zhao1, Lixin Xie1, Yuxin Wang1, Jing Chen2   

  1. 1. Key Laboratory of Membrane Science & Desalination Technology, State Key Laboratory of Chemical Engineering, School of Chemical Engineering, Tianjin University, Tianjin 300350, China;
    2. Institute of Nuclear and New Energy Technology, Collaborative Innovation Center of Advanced Nuclear Technology, Tsinghua University, Beijing 102201, China
  • Received:2016-10-11 Revised:2016-12-16 Online:2017-02-15 Published:2017-04-10
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No.U1430234), the Science and Technology Program of Tianjin (No.16JCQNJC06000) and the National Key Technology Support Program(No. 2015BAB10B00).
锂是重要的能源金属，从盐湖和海水卤水等液态锂资源中提锂，是获取锂资源的重要方向。吸附法适合从低浓度大体积的液相中选择性提取锂离子，而吸附材料是吸附提锂的核心。本文从吸附材料的类别出发，对吸附材料的最新研究进展进行综述，包括天然矿石和碳材料、无机锂离子筛（锰系、钛系锂离子筛）及成型方法、有机配体（冠醚、杯芳烃、磷酸酯等）复合吸附材料和材料的基体选择等内容，分析了各类吸附材料的提锂机理和吸附性能，为研究新型提锂吸附剂、开发新的吸附分离体系、克服吸附法的缺点和推动吸附技术在液态锂资源提取领域的发展提供参考。
关键词： 海水, 盐湖卤水, 提锂, 吸附材料
Lithium is a very important metal resource for lithium-ion batteries and nuclear industries. With the fast-growing market demand for lithium, the focus of lithium extraction technologies has shifted to aqueous lithium resources, such as seawater and salt lake brine. Adsorption method has been recognized as one of the most suitable technologies for recovery of lithium from aqueous resources. The present paper reviews the development of the adsorption materials of lithium ion comprehensively, including the inorganic adsorbents (the natural ores, carbon materials, Mn or Ti lithium ion-sieves and their forming techniques) and organic composite adsorbents. The organic ligand functional groups (crown ether, calixarene and phosphate) for lithium ion adsorption, and their bonded matrixs are also summarized. The adsorption mechanism, adsorption capacity and selectivity of dififferent adsorption materials are compared. This paper provides a reference for developing of novel adsorption materials and separation systems to extract lithium ion from aqueous brine resources.

Contents
1 Introduction
2 Inorganic materials for adsorption of lithium
2.1 Natural ores and carbon materials
2.2 Lithium ion sieves
2.3 Lithium ion sieves composite materials
3 Composite materials for adsorption of lithium
3.1 Organo-functional groups of composite materials
3.2 Matrixes of composite materials
3.3 Composite materials with lithium ion imprinting technology
4 Conclusion

Key words: seawater, salt lake brine, extraction of lithium, adsorption materials

中图分类号: 

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