English
往期目录
新闻公告
More
化学进展 2015, Vol. 27 Issue (1): 125-134 DOI: 10.7536/PC140819 前一篇   

• 综述与评论 •

硼吸附材料及其性能

张茜, 任其龙, 杨亦文, 邢华斌, 苏宝根, 鲍宗必*   

  1. 浙江大学生物质化工教育部重点实验室 浙江大学化学工程与生物工程学系 杭州 310027
  • 收稿日期:2014-08-01 修回日期:2014-10-01 出版日期:2015-01-15 发布日期:2014-11-24
  • 通讯作者: 鲍宗必 E-mail:baozb@zju.edu.cn
  • 基金资助:

    国家自然科学基金项目(No. 21376205, U1407134),浙江省自然科学基金项目(No. Y13B060004)和中央高校基本科研业务费专项(No. 2014FZA4021)资助

下载PDF ( 1996 ) 引用
导出 被引次数 ( 7 | 2 )

Materials for Boron Adsorption

Zhang Xi, Ren Qilong, Yang Yiwen, Xing Huabin, Su Baogen, Bao Zongbi*   

  1. Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
  • Received:2014-08-01 Revised:2014-10-01 Online:2015-01-15 Published:2014-11-24
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No. 21376205, U1407134), the Natural Science Foundation of Zhejiang Province(No. Y13B060004) and the Foundamental Research Funds for the Central Universities(No. 2014FZA4021).

硼酸作为一种重要的化学品,广泛应用于工业生产及高尖端技术领域。由于在其生产和应用过程中产生大量含硼废水,从水溶液中回收或脱除硼对资源的重复利用、降低环境污染等都有重要意义。吸附法提硼具有深度脱硼、杂质去除彻底、吸附剂可循环利用和工艺简单等优势,是一种高效脱硼方法,其核心问题在于设计与制备硼吸附容量大、机械强度高且易再生的吸附材料。本文综述了近年来国内外硼吸附材料的类型及其吸附性能,按照吸附功能团的结构将硼吸附材料进行划分,着重介绍了目前应用最广的葡甲胺类吸附剂和最具发展前景的含双酚羟基功能团的吸附剂的研究与应用情况,同时介绍了新型有机-无机杂化硼吸附材料,并指出了今后硼吸附材料的发展趋势,为盐湖卤水提硼、淡化海水脱硼和废水除硼等应用开发中硼吸附材料的选择提供重要参考。

关键词： 硼, 吸附材料, 葡甲胺, 杂化材料, 活性双羟基

Boric acid, as an important boron compound, has been widely used in industrial production and cutting-edge technology. Massive wastewater containing boron were discharged during the industrial process. Adsorption technique is an efficient method for removal or recovery of boron from aqueous solutions as it has advantages of high boron recovery, renewable adsorbents and easy operation. The key to the adsorption process is the the selection of adsorbents with high adsorption capacity, acceptable mechanical strength and regeneration capability. In this review, we mainly review different kinds of boron-selective adsorbents reported in recent years and their adsorption performances. Boron adsorbents are catalogued by their functional groups. Among the reported adsorbents, the most widely used N-methyl-D-glucamine (NMDG) functionalized adsorbents are extensively demonstrated, and the adsorbents with structure of diols binding phenolic moiety are discussed. Moreover, other organic-inorganic hybrid adsorbents are introduced. This review may be helpful to the design of novel high-performance adsorbents for boron recovery or removal from aqueous solutions such as from salt lake brine and desalinize seawater.

Contents
1 Introduction
2 NMDG functionalized adsorbents
2.1 NMDG functionalized organic resins
2.2 NMDG functionalized organic-inorganic hybrid materials
3 Other active diols functionalized adsorbents
3.1 Polymeric adsorbents
3.2 Phenolic adsorbents
4 Inorganic adsorbents
4.1 Magnesium hydroxide
4.2 Hydroxide of aluminum, iron, calcium
5 Natural adsorbents
6 Conclusion and outlook

Key words: boron, adsorption materials, N-methyl-D-glucamine (NMDG), hybrid materials, active diols

中图分类号: 

()

[1] 龚立(Gong L),程理(Cheng L),郑军华(Zheng J H),侯运然(Hou Y R),马小敏(Ma X M),姚永泉(Yao Y Q). 辐射防护(Radiation Protection), 1995(01): 33.
[2] 刘化政(Liu H Z). 中国农业科学院硕士论文(Graduate Dissertation of the Chinese Academy of Agricultural Sciences), 2008.
[3] Organization W H. Guidelines for Drinking-Water quality: Recommendations. World Health Organization, 2004.
[4] 王晓伟(Wang X W),杨开(Yang K),贾铭椿(Jia M C). 水处理技术(Technology of Water Treatment), 2010(08): 6.
[5] 熊妍(Xiong Y),鲍宗必(Bao Z B),邢华斌(Xing H B),苏宝根(Su B G),杨亦文(Yang Y W),任其龙(Ren Q L). 化工学报(CIESC Journal), 2012(11): 3546.
[6] Kemp P H, Emeleus H J. The Chemistry of Borates, Part 1: A Review. Borax Consolidated Limited, 1956.
[7] Marston C, Busch M, Prabhakaran S. A Boron-Selective Resin for Seawater Desalination. Proceedings of European Desalination Society Conference on Desalination and the Enviroment,Santa Margerita Ligure,Italy, 2005.
[8] Melnyk L, Goncharuk V, Butnyk I, Tsapiuk E. Desalination, 2005, 185(1): 147.
[9] 肖湘(Xiao X), 陈白珍(Chen B Z), 石西昌(Shi X C), 陈亚(Chen Y). Journal of Central South University, 2012(10): 2768.
[10] 王美玲(Wang M L),王贯春(Wang G C),付道贵(Fu D G),简敏(Jian M),刘晓珍(Liu X Z),邹从沛(Zou C P). 核动力工程(Nuclear Power Engineering), 2012(S2): 120.
[11] 何天明(He T M),陈白珍(Chen B Z),石西昌(Shi X C),徐徽(Xu H),肖湘(Xiao X). 中南大学学报(自然科学版)(Journal of Central South University), 2011(06): 1538.
[12] 肖湘(Xiao X). 中南大学博士论文(Doctoral Dissertation of Central South University), 2013.
[13] 王美玲(Wang M L),邹从沛(Zou C P),付道贵(Fu D G),王冠春(Wang G C),刘晓珍(Liu X Z),万玉华(Wan Y H). 全国核材料学术交流会论文集(Proceedings of National Conference of Nuclear Materials).成都(Chengdu), 2006.5.
[14] 何天明(He T M). 中南大学硕士论文(Graduate Dissertation of Central South University), 2010.
[15] Yan C, Yi W, Ma P, Deng X, Li F. Journal of Hazardous Materials, 2008, 154(1/3): 564.
[16] Y?lmaz I, Kabay N, Yüksel M. Desalination, 2013, 310: 151.
[17] Kabay N, Y?lmaz I, Yamac S, Samatya S, Yuksel M, Yuksel U, Arda M, Sa D?lam M, Iwanaga T, Hirowatari K. React. Funct. Polym., 2004, 60: 163.
[18] Kabay N, Yilmaz I, Yamac S, Yuksel M, Yuksel U, Yildirim U, Aydogdu O, Iwanaga T, Hirowatari K. Desalination, 2004, 167: 427.
[19] Harada A, Takagi T, Kataoka S, Yamamoto T, Endo A. Adsorption, 2011, 17: 171.
[20] Nishihama S, Sumiyoshi Y, Ookubo T, Yoshizuka K. Desalination, 2013, 310: 81.
[21] Bicak N, Bulutcu N, Senkal B, Gazi M. Reactive and Functional Polymers, 2001, 47(3): 175.
[22] Bicak N, Oezbelge H O, Yilmaz L, Senkal B F. Macromolecular Chemistry and Physics, 2000, 201(5): 577.
[23] 王丽娜(Wang L N),齐涛(Qi T),李会泉(Li H Q),张懿(Zhang Y). 过程工程学报(The Chinese Journal of Process Engineering), 2004, 4(06): 502.
[24] Wang L, Qi T, Gao Z, Zhang Y, Chu J. Reactive and Functional Polymers, 2007, 67(3): 202.
[25] Samatya S, Kabay N, Tuncel A. Journal of Applied Polymer Science, 2012, 126(4): 1475.
[26] Harada A, Takagi T, Kawai A, Endo A. Adsorption, 2013, 19(1): 1.
[27] Ikeda K, Umeno D, Saito K, Koide F, Miyata E, Sugo T. Industrial & Engineering Chemistry Research, 2011, 50(9): 5727.
[28] Ting T, Hoshina H, Seko N, Tamada M. Desalination and Water Treatment, 2013, 51(13/15): 2602.
[29] Shi Q, Meng J, Xu R, Du X, Zhang Y. Journal of Membrane Science, 2013, 444: 50.
[30] Li X, Liu R, Wu S, Liu J, Cai S, Chen D. Journal of Colloid and Interface Science, 2011, 361(1): 232.
[31] Xu L, Liu Y, Hu H, Wu Z, Chen Q. Desalination, 2012, 294: 1.
[32] Sanfeliu C, Martínez-Máñez R, Sancenón F, Soto J, Puchol V, Amorós P, Marcos M D. Journal of Materials Chemistry, 2012, 22(48): 25362.
[33] Kaftan Ö, Aç?kel M, Ero D?lu A E, Shahwan T, Artok L, Ni C. Analytica Chimica Acta, 2005, 547(1): 31.
[34] Wang L, Qi T, Zhang Y. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2006, 275(1/3): 73.
[35] Fried D I, Schlossbauer A, Bein T. Microporous and Mesoporous Materials, 2012, 147(1): 5.
[36] Liu H, Ye X, Li Q, Kim T, Qing B, Guo M, Ge F, Wu Z, Lee K. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2009, 341(1/3): 118.
[37] Liu H, Qing B, Ye X, Guo M, Li Q, Wu Z, Lee K, Lee D, Lee K. Current Applied Physics, 2009, 9(4): e280.
[38] 刘海宁(Liu H N). 中国科学院研究生院博士论文(Doctoral Dissertation of the Chinese Academy of Sciences), 2009.
[39] Senkal B F, Bicak N. Reactive and Functional Polymers, 2003, 55(1): 27.
[40] Bicak N, Gazi M, Senkal B F. Reactive and Functional Polymers, 2005, 65(1/2): 143.
[41] Gazi M, Bicak N. Reactive and Functional Polymers, 2007, 67(10): 936.
[42] Yavuz E, Gursel Y, Senkal B F. Desalination, 2013, 310: 145.
[43] Gazi M, Galli G, Bicak N. Separation and Purification Technology, 2008, 62(2): 484.
[44] Çelik Z C, Can B Z, Kocakerim M M. Journal of Hazardous Materials, 2008, 152(1): 415.
[45] Miyazaki Y, Matsuo H, Fujimori T, Takemura H, Matsuoka S, Okobira T, Uezu K, Yoshimura K. Polyhedron, 2008, 27(13): 2785.
[46] Can B Z, Ceylan Z, Kocakerim M M. Desalination and Water Treatment, 2012, 40(1/3): 69.
[47] Yu S, Xue H, Fan Y, Shi R. Chemical Engineering Journal, 2013, 219: 327.
[48] Morisada S, Rin T, Ogata T, Kim Y, Nakano Y. Water Research, 2011, 45(13): 4028.
[49] Erdem P, Bursali E A, Yurdakoc M. Environmental Progress & Sustainable Energy, 2013, 32(4): 1036.
[50] Ruiz M, Tobalina C, Demey-Cedeño H, Barron-Zambrano J A, Sastre A M. Reactive and Functional Polymers, 2013, 73(4): 653.
[51] Suzuki T A M, Tanaka D A P, Yokoyama T, Miyazaki Y, Yoshimura K. Journal of the Chemical Society, Dalton Transactions, 1999(10): 1639.
[52] de la Fuente García-Soto M M, Mu Oz Camacho E. Desalination, 2009, 249(2): 626.
[53] 张国政(Zhang G Z),李永强(Li Y Q),赵蓬(Zhao P),唐林生(Tang L S). 盐业与化工(Journal of Salt and Chemical Industry), 2011, 40(1): 12.
[54] Kipcak I, Ozdemir M. Chemical Engineering Journal, 2012, 189/190: 68.
[55] Demetriou A, Pashalidis I. Desalination and Water Treatment, 2012, 37(1/3): 315.
[56] Seki Y, Seyhan S, Yurdakoc M. Journal of Hazardous Materials, 2006, 138(1): 60.
[57] Demetriou A, Pashalidis I, Nicolaides A V, Kumke M U. Desalination and Water Treatment, 2013, 51(31/33): 6130.
[58] Ozturk N, Kavak D. Journal of Hazardous Materials, 2005, 127(1): 81.
[59] Cengeloglu Y, Tor A, Arslan G, Ersoz M, Gezgin S. Journal of Hazardous Materials, 2007, 142(1): 412.
[60] Liu R, Ma W, Jia C, Wang L, Li H. Desalination, 2007, 207(1): 257.
[61] Kavak D. Journal of Hazardous Materials, 2009, 163(1): 308.
[62] Polowczyk I, Ulatowska J, Ko D?lecki T, Bastrzyk A, Sawiński W. Desalination, 2013, 310: 93.
[63] Kehal M, Reinert L, Duclaux L. Applied Clay Science, 2010, 48(4): 561.
[64] Irawan C, Liu J C, Wu C. Desalination, 2011, 276(1/3): 322.
[65] Man H C, Chin W H, Zadeh M R, Yusof M R M. BioResources, 2012, 7(3): 3810.
[66] Kluczka J, Korolewicz T, Zo?otajkin M, Simka W, Raczek M. Environmental Technology, 2013, 34(11): 1369.
[67] Sasaki T, Sakai Y, Hongo T, Iizuka A, Yamasaki A. Industrial & Engineering Chemistry Research, 2012, 51(16): 5813.
[1] 曾毅, 任永生, 马文会, 陈辉, 詹曙, 曹静. 冶金法生产太阳能级硅的除硼方法、技术及工艺[J]. 化学进展, 2022, 34(4): 926-949.
[2] 顾婷婷, 顾坚, 张喻, 任华. 金属硼氢化物基固态储氢体系[J]. 化学进展, 2020, 32(5): 665-686.
[3] 姚淇露, 杜红霞, 卢章辉. 氨硼烷催化水解制氢[J]. 化学进展, 2020, 32(12): 1930-1951.
[4] 牟泽怀, 王银军, 谢鸿雁. 稀土金属配合物催化芳香型乙烯基极性单体立构选择性聚合[J]. 化学进展, 2020, 32(12): 1885-1894.
[5] 杨智文, 詹迎迎, 籍少敏, 杨庆旦, 李琦, 霍延平. 含硼有机发光二极管材料与器件[J]. 化学进展, 2019, 31(6): 906-928.
[6] 王睿, 台国安, 伍增辉, 邵伟, 候闯, 郝金钱. 硼纳米结构的理论和实验研究[J]. 化学进展, 2019, 31(12): 1696-1711.
[7] 张浩, 许芳, 王合营, 姜涛, 马志. 基于聚亚甲基的新型共聚物的可控合成[J]. 化学进展, 2018, 30(2/3): 179-189.
[8] 张世亮, 姚淇露, 卢章辉*. 肼硼烷的合成及产氢[J]. 化学进展, 2017, 29(4): 426-434.
[9] 孔龙娟, 李晖*. 衬底调制下的硼墨烯、硅烯、锗烯等单元素二维材料的原子与电子结构[J]. 化学进展, 2017, 29(4): 337-347.
[10] 张文, 牟英炘, 赵颂, 解利昕, 王宇新, 陈靖. 液态锂资源提锂的吸附材料及性能[J]. 化学进展, 2017, 29(2/3): 231-240.
[11] 茹静, 耿璧垚, 童聪聪, 王海英, 吴胜春, 刘宏治. 纳米纤维素基吸附材料[J]. 化学进展, 2017, 29(10): 1228-1251.
[12] 杨露姣, 张颖, 程璇. 先驱体转化法制备硅硼碳氮陶瓷的结构与性能[J]. 化学进展, 2016, 28(2/3): 308-316.
[13] 沈艳芳, 徐畅, 黄敏, 王海燕, 程龙玖. 硼团簇、硼烷及金属硼化物的研究现状[J]. 化学进展, 2016, 28(11): 1601-1614.
[14] 杨正龙, 徐晓黎, 赵宇馨. 硫醇-烯/炔点击化学制备有机/无机杂化材料[J]. 化学进展, 2014, 26(06): 996-1004.
[15] 张磊, 涂倩, 陈学年, 刘蒲. 氨硼烷释氢纳米金属催化剂的研究[J]. 化学进展, 2014, 26(05): 749-755.
阅读次数
全文


摘要

硼吸附材料及其性能