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化学进展 2017, Vol. 29 Issue (10): 1228-1251 DOI: 10.7536/PC170616 前一篇   后一篇

• 综述 •

纳米纤维素基吸附材料

茹静1,2, 耿璧垚1,2, 童聪聪1,2, 王海英3, 吴胜春3, 刘宏治1,2*   

  1. 1. 浙江农林大学工程学院 杭州 311300;
    2. 浙江省竹资源与高效利用协同创新中心 杭州 311300;
    3. 浙江农林大学环境与资源学院 杭州 311300
  • 收稿日期:2017-06-13 修回日期:2017-08-12 出版日期:2017-10-15 发布日期:2017-08-29
  • 通讯作者: 刘宏治,e-mail:hzliu@iccas.ac.cn,hongzhil@zafu.edu.cn E-mail:hzliu@iccas.ac.cn,hongzhil@zafu.edu.cn
  • 基金资助:
    浙江省级公益技术应用研究项目（No.2016C33029，2017C33113）和浙江农林大学科研发展基金项目（No.2013FR088）资助
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Nanocellulose-Based Adsorption Materials

Jing Ru1,2, Biyao Geng1,2, Congcong Tong1,2, Haiying Wang3, Shengchun Wu3, Hongzhi Liu1,2*   

  1. 1. School of Engineering, Zhejiang Agriculture and Forestry University, Hangzhou 311300, China;
    2. Zhejiang Provincial Collaborative Innovation Center for Bamboo Resources and High-efficiency Utilization, Hangzhou 311300, China;
    3. School of Environment & Resource Sciences, Zhejiang Agriculture and Forestry University, Hangzhou 311300, China
  • Received:2017-06-13 Revised:2017-08-12 Online:2017-10-15 Published:2017-08-29
  • Supported by:
    The work was supported by the Public Welfare Projects of Zhejiang Province (No. 2016C33029, 2017C33113) and the Scientific Research Foundation of Zhejiang Agriculture and Forestry University (No. 2013FR088).
纳米纤维素是一大类微纤单元直径在纳米级（2~100 nm）的新型纤维素材料，因其长径比高、比表面积大、力学性能优异及表面易于化学修饰，成为现今生物质吸附材料领域的研究热点。本文总结了近年来纳米纤维素基吸附材料方面的研究成果，介绍了以纳晶纤维素（NCC）、纳纤化纤维素（NFC）以及细菌纤维素（BC）为基材的吸附材料，及其在移除染料、重金属、CO2气体和其他污染物（如抗生素、芳香族有机物、放射性元素、易挥发的有毒有机物）的研究进展。最后，本文对纳米纤维素基吸附材料存在的问题进行探讨，并对其未来发展前景进行了展望。
关键词： 纳米纤维素, 纳米复合材料, 吸附材料, 水体污染物, CO2吸附
Nanocellulose refers to a family of novel cellulose materials with the nanosized (2~100 nm) cellulose microfibrils in diameter. Because of the high aspect ratio, large specific surface area, exceptional mechanical properties as well as ease for surface modification, nanocelluose has become a research focus of biosorbent materials areas. In this article, the achievements in the nanocellulose-absorbent materials in recent years are summarized, and the research progress of absorbent materials based on nanocrystalline cellulose (NCC), nanofibrillated cellulose (NFC), and bacterial cellulose (BC) in the aspects of removing dyes, heavy metal ions, CO2 gas, and other pollutants (e.g. antibiotics, aromatic organic compounds, radioactive elements, and volatile organic compounds), are reviewed, respectively. Besides, the existing problems of nanocellulose-based adsorbent materials are discussed, and their future development prospects are presented.
Contents
1 Introduction
2 Dye adsorbents
2.1 NCC-based adsorbents
2.2 NFC-based adsorbents
2.3 BC-based adsorbents
3 Heavy metal ions adsorbents
3.1 NCC-based adsorbents
3.2 NFC-based adsorbents
3.3 BC-based adsorbents
4 CO2 adsorbents
5 Nanocellulose-based adsorbents for other pollutants
5.1 Antibiotics adsorbents
5.2 Aromatic organic compound adsorbents
5.3 Radioactive element adsorbents
5.4 Volatile organic compound adsorbents
6 Conclusion
Key words: nanocellulose, nanocomposites, adsorption material, water pollutant, CO2 adsorption

中图分类号: 

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纳米纤维素基吸附材料