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木质素:一种有潜力的生物质基催化剂来源
陈祥云, 袁冰, 于凤丽, 解从霞, 于世涛
化学进展, 2021, 33(2): 303-317.   DOI: 10.7536/PC200524

Raw
materials
Catalysts Activator/dopant Processing
temperature,℃
BET surface
area, m2·g-1
Reactions ref
AL N-S-C 900 - 900 486 Oxygen reduction reaction(ORR) 151
Lignin Lignin derived multi-doped(N, S, Cl) carbon materials NaCl/ZnCl2 1000 1289 ORR 152
Low-sulfur lignin Sulfur-nitrogen co-doped porous biocarbon catalyst NaCl/ZnCl2 1000 1218.68 Electrochemical CO2 reduction
reaction(ECRR)
153
Lignin Pt/Lg-CDs-800 - 800 - Methanol electro-oxidation reaction(MOR) 154
Kraft lignin Pd-activated carbon catalysts H3PO4 900 1248 Suzuki-Miyaura cross-coupling
reaction and hydrogenation
155
Eucalyptus lignin High-Performance Magnetic Activated Carbon KOH 800 2875 Magnetic activated carbons(MACE) 156
MACE High-Performance Magnetic Activated Carbon-NiMo Supports KOH 800 2875 Hydrodeoxygenation(HDO) 157
SLS Co3S4/C
NiS/C
MoS2/C
Co3Mo6S/C
NiMoS3/C
S/C
Mg(OH)2 700 379
560
630
485
412
571
HDO 158
DAL Mo-DAL - 800 19.7 Hydrogen production from formic acid 159
Lignin A single-atom cobalt over nitrogen-doped carbon(Co SAs/N@C) Zn(OAC)2·2H2O 900 - Transformation of 5-HMF and furfural into the carboxylic acids. 160
AL Co-Mn/N@C Dicyandiamide 800 - Aerobic oxidation of 5-
hydroxymethylfurfural to 2,5-
furandicarboxylic acid
161
AL M SAs-N@C, M=Fe, Co, Ni, Cu Dicyandiamide
Zn(OAC)2·2H2O
1000 - Oxidative esterification of primary alcohols 162
SLS N,S-doped hierarchical porous catalysts(Co-Nx/Sy-C) Thiourea 900 314 Peroxymonosulfate-based oxidative
degradation and borohydride-
mediated reductive amination of
several pollutants
163
表4 木质素碳基氧化还原催化剂的制备及应用
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