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化学进展 2003, Vol. 15 Issue (03): 204- 前一篇   后一篇

• 综述与评论 •

多相不对称催化氢化研究进展*

李晓红;李灿**   

  1. （中国科学院大连化学物理研究所 催化基础国家重点实验室 大连 116023）
  • 收稿日期:2001-12-01 修回日期:2002-12-01 出版日期:2003-05-24 发布日期:2003-05-24
  • 通讯作者: 李灿
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Progress in Enantioselective Hydrogenation on Heterogeneous Catalysts

Li Xiaohong;Li Can**   

  1. (State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China)
  • Received:2001-12-01 Revised:2002-12-01 Online:2003-05-24 Published:2003-05-24
  • Contact: Li Can
本文综述了多相不对称催化氢化反应的最新研究进展.特别是对最近几年来两个典型的多相不对称催化氢化体系即酒石酸盐修饰镍催化剂催化β-酮酸酯的不对称氢化反应体系和金鸡纳生物碱修饰铂催化剂催化α-酮酸酯的不对称氢化反应体系进行了详细的介绍和讨论,同时展望了多相不对称催化氢化反应研究的前景.
关键词： 不对称氢化, 多相催化, 金鸡纳生物碱, 酒石酸, 镍、铂催化剂
The research progress in enantioselective hydrogenation catalyzed by heterogeneous catalysts is reviewed. Two typical examples, asymmetric hydrogenation of α,β-ketoesters on nickel catalysts modified with tartaric acid derivatives and on platinum catalysts modified with cinchona alkaloids are introduced and discussed in detail. The prospect for enantioselective hydrogenation on heterogeneous catalysts is also proposed.
Key words: enantioselective hydrogenation, heterogeneous catalysis, cinchona alkaloids, tartaric acid, nickel and platinum catalysts

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摘要

多相不对称催化氢化研究进展*