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化学进展 2018, Vol. 30 Issue (7): 879-887 DOI: 10.7536/PC180222 前一篇   后一篇

• 综述 •

超分子组装体系中基于三重态-三重态湮灭的上转换发光

范鸿川1,2, 杨东1,2, 段鹏飞1*   

  1. 1. 国家纳米科学中心 中国科学院纳米科学卓越创新中心 中国科学院纳米系统与多级次制造重点实验室 北京 100190;
    2. 中国科学院大学材料科学与光电技术学院 北京 101408
  • 收稿日期:2018-02-26 修回日期:2018-04-27 出版日期:2018-07-15 发布日期:2018-05-16
  • 通讯作者: 段鹏飞 E-mail:duanpf@nanoctr.cn
  • 基金资助:
    国家自然科学基金项目（No.51673050）资助
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Triplet-Triplet Annihilation-Based Upconversion in Supramolecular System

Hongchuan Fan1,2, Dong Yang1,2, Pengfei Duan1*   

  1. 1. Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology(NCNST), Beijing 100190, China;
    2. College of Materials Science and Optoelectronic Technology, University of Chinese Academy of Sciences, Beijing 101408, China
  • Received:2018-02-26 Revised:2018-04-27 Online:2018-07-15 Published:2018-05-16
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No. 51673050).
超分子组装实质上是对分子的精密组织和调控，结合三重态-三重态湮灭上转换发光，能够调控分子激发态能量的转移，提高上转换效率。本文综述了超分子组装体系中上转换发光的研究进展，包括基于有机凝胶、亲疏溶剂组装的超分子膜、纳米颗粒、聚合物薄膜以及主-客体配位超分子等体系。这些超分子体系为上转换发光提供了良好的基质，取代了传统三重态-三重态湮灭上转换发光的溶液体系，既解决了由于染料溶解性导致的聚集荧光猝灭，又有效地阻隔了氧气，同时，将上转换发光体系固体化而便于集成到器件等各个应用领域。值得注意的是，不同的超分子组装体系中的上转换发光，有着温度响应，可逆开/关效应，甚至是将光能转化为机械能的特性。
关键词： 超分子组装, 三重态-三重态湮灭, 上转换发光, 有机凝胶
Self-assembly is an essential process that can precisely organize molecules into supramolecular systems by artificial control. Introducing this concept into triplet-triplet annihilation-based upconversion(TTA-UC) system, triplet-triplet energy transfer and triplet-triplet annihilation can be regulated easily, thus the upconversion emission efficiency might be significantly improved. This review concentrates on the research progress about supramolecular system-based TTA-UC, including organogel, membrane, nanoparticles, polymer films, host-guest complexes, etc. Instead of conventional solution system, supramolecular systems provide ideal matrixes, which not only avoid the fluorescence quenching caused by aggregation and phase-segregation of dye molecules, but also prevent the triplet oxygen caused quenching. Meanwhile, supramolecular systems are facile enough to integrate TTA-UC system into devices. Furthermore, integrating TTA-UC and different supramolecular systems, variety properties can be achieved, such as temperature responsibility, all-or-none switching, and so on. In brief, supramolecular systems make TTA-UC system more potential to be applied in many fields, such as photonic devices, solar cell, nano-medical, bio-imagining and so forth.
Contents
1 Introduction
2 Triplet-triplet annihilation-based photon upconversion
3 Research progress of the upconvertion supramolecular systems
3.1 Upconversion in gel system
3.2 Upconversion in membrane system
3.3 Upconversion in polymer nanoparticle system
3.4 Upconversion in host-guest complex system
3.5 Upconversion in polymer film system
4 Conclusion and outlook
Key words: supramolecular assembly, triplet-triplet annihilation, photon upconversion, organogel

中图分类号: 

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