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氨/醛基金属有机骨架材料合成及其在吸附分离中的应用
闫保有, 李旭飞, 黄维秋, 王鑫雅, 张镇, 朱兵
化学进展, 2022, 34(11): 2417-2431.   DOI: 10.7536/PC220302

ICPSM-MOF Reaction conditions Application areas Mechanism ref
UiO-66-PTC 80℃, 36 h Pb(Ⅱ) Chelation of S、N with Pb(Ⅱ) 107
ZIF-90-OM 60℃, 24 h U(Ⅳ) Interaction between oxygen in -CHO、Zn-OH and N-OH and U(Ⅳ) 108
ZIF-90-ABOA 100℃, 24 h U(Ⅳ) Chelation of amine oxime group with U(Ⅳ) 109
ZIF-90-SH 60℃, 24 h Hg(Ⅱ) Chelation of S、N with Hg(Ⅱ) 106
TSC-ZIF 100℃, 24 h Hg(Ⅱ) Chelation of S、N with Hg(Ⅱ) 75
MIL-101(Cr)-N-2-pyc 40℃, 12 h ANI、FUR、BPA Hydrogen bonding, π-π bonding interactions and electrostatic gravity 47
ZIF-POSS 80℃, 24 h Organic solvents (n-hexane,
toluene, chloroform, sec-
butanol)/water
Hydrophobic, lipophilic 114
M5C 180℃, 12 h AO、RB Electrostatic interactions, van der Waals forces, hydrogen bonding, the Lewis acid-base and π-π bond interactions 113
表4 典型的ICPSM-MOF材料的反应条件、应用领域及作用机理
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