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化学进展 2004, Vol. 16 Issue (05): 776- 前一篇   后一篇

• 综述与评论 •

硫脲类阴离子受体的研究进展*

吴芳英1,2;温珍昌1;江云宝1**   

  1. (1.厦门大学化学系 现代分析科学教育部重点实验室 厦门 361005; 2.南昌大学化学系 南昌 330047)

  • 收稿日期:2003-06-01 修回日期:2003-07-01 出版日期:2004-10-14 发布日期:2004-10-14
  • 通讯作者: 江云宝
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Thiourea-based Receptors for Anion Recognition and Sensing

Wu Fangying1,2;Wen Zhenchang1;Jiang Yunbao1**

  

  1. (1.Department of Chemistry and the MOE Key Laboratory of Analytical Sciences, Xiamen University, Xiamen 361005, China; 2.Department of Chemistry,Nanchang University, Nanchang 310047, China)
  • Received:2003-06-01 Revised:2003-07-01 Online:2004-10-14 Published:2004-10-14
  • Contact: Jiang Yunbao
阴离子识别是超分子化学研究的重要内容之一,其关键环节是构筑可识别阴离子的结合受体,后者以非共价键力如静电作用、疏水作用、氢键等与阴离子结合.本文详细评述了近5年来硫脲类阴离子识别受体的设计、结构及其阴离子识别作用的研究进展.
关键词： 硫脲衍生物, 阴离子受体, 阴离子识别
Anion recognition and sensing have been developed into an important research subject in supramolecular chemistry. Noncovalent interactions such as hydrogen bonding, electrostatic interaction, hydrophobic interaction, etc. are the most important binding forces existing in the anion-receptor binding complexes, which forms the basis of designing anion binding receptors. The design, construction and anion recognition and sensing of thiourea-based receptors following mainly multi hydrogen bonding interactions are reviewed. 51 key references were cited to represent the related advances in the past 5 years.
Key words: thioureas, anion receptor, anion recognition, anion sensing

中图分类号: 

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摘要

硫脲类阴离子受体的研究进展*