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化学进展 2015, Vol. 27 Issue (5): 559-570 DOI: 10.7536/PC141108 前一篇   后一篇

所属专题： 电化学有机合成

• 综述与评论 •

基于脲衍生物阴离子识别的电化学检测

李敏睿*, 郭永亮, 杨保平, 郭军红, 崔锦峰   

  1. 兰州理工大学石油化工学院 兰州 730050
  • 收稿日期:2014-11-01 修回日期:2015-01-01 出版日期:2015-05-15 发布日期:2015-03-16
  • 通讯作者: 李敏睿 E-mail:liminrui@lut.cn
  • 基金资助:
    甘肃省自然科学基金青年基金项目(No. 1212RJYA018)资助
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Electrochemical Analyses of Anion Recognition Based on Urea Derivatives

Li Minrui*, Guo Yongliang, Yang Baoping, Guo Junhong, Cui Jinfeng   

  1. College of Petrochemical Technology, Lanzhou University of Technology, Lanzhou 730050, China
  • Received:2014-11-01 Revised:2015-01-01 Online:2015-05-15 Published:2015-03-16
  • Supported by:
    The work was supported by the Natural Science Foundation of Gansu Province (No. 1212RJYA018).
作为优良的氢键给予体,脲基(—NH—CO—NH—)是构筑阴离子识别受体的理想结构单元.而电化学方法因其方便快捷、灵敏度高等优点,近年来被广泛应用于阴离子的识别检测.本文对脲类受体的电化学阴离子识别进行了讨论,主要包括:(i) 归纳整理了电化学阴离子识别的机理,包括识别位点与阴离子结合之后对氧化还原中心的5种扰动机理和溶液中电化学测试受体和阴离子相互作用时常见现象的分析及对应结合常数的计算; (ii) 电活性脲类阴离子受体的研究进展,包括受体分子的设计、识别和机理; (iii) 探讨了该领域的后续发展方向.
关键词： 阴离子识别, 脲, 电化学传感器
As an excellent hydrogen-bond donor, urea is a kind of ideal unit for constructing anion recognition receptors based on multiple hydrogen bonds. Electrochemical technology has been widely applied in anion binding in recent years due to its rapid, sensitive and convenient measurement. This review summarizes some distinctive aspects of electrochemical analyses of anion recognition based on urea derivatives:(i) we aim to illustrate the mechanisms and methodologies of electrochemical experiments about the interactions between urea receptors modified by the redox-active center and anions in solution, (ii) the most recent advances in the field are also detailed including design, synthesis and the interpretation of the solution behavior, and (iii) the trends of development in this field are discussed.

Contents
1 Introduction
2 Mechanism of electrochemical analyses of anion recognition
3 Anion receptors with redox unit
3.1 Anion receptors based on ferrocene
3.2 Others
4 Prospects

Key words: anion recognition, urea, electrochemical sensor

中图分类号: 

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