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化学进展 2004, Vol. 16 Issue (05): 758- 前一篇   后一篇

• 综述与评论 •

温和条件下液态醇催化氧化制醛、酮

陈琳;许传芝;夏春谷*;冯艳华   

  1. (中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室 兰州 730000

    兰州大学化学化工学院 兰州 730000)

  • 收稿日期:2003-09-01 修回日期:2004-01-01 出版日期:2004-10-14 发布日期:2004-10-14
  • 通讯作者: 夏春谷
下载PDF ( 2484 ) 引用
导出 被引次数 ( 39 | 3 )

Advances in Oxidations of Liquid Alcohols into the Corresponding Carbonyls under Mild Conditions

Chen Lin;Xu Chuanzhi;Xia Chungu*;Feng Yanhua   

  1. (State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

    College of Chemistry & Chemical Engineering, Lanzhou University;Lanzhou 730000, China)

  • Received:2003-09-01 Revised:2004-01-01 Online:2004-10-14 Published:2004-10-14
  • Contact: Xia Chungu
本文对温和条件下液态醇催化氧化制醛或酮的研究进展进行了全面评述,介绍了均相催化剂、液固多相催化剂、有机相-水相两相催化剂、氟两相催化剂和离子液相催化剂,着重讨论了以O_2为氧源的催化体系.
关键词： 液态醇, 催化氧化, 均相催化, 液固多相催化, 水-有机两相催化, 氟两相催化, 离子液催化
A review is presented on the progress in catalytic oxidation of liquid alcohols into the corresponding carbonyls under mild conditions. The homogeneous catalysts, liquid-solid heterogeneous catalysts, organic/aqueous biphasic catalysts, flourous biphasic catalysts and ionic liquid phase catalysts are descrided. The emphasis is placed on the catalytic systems with O_2 as the oxidant.
Key words: liquid alcohol, catalytic oxidations, homogeneous catalysis, liquid-solid heterogeneous catalysis, organic/aqueous biphasic catalysis, flourous biphasic catalysis, ionic liquid catalysis

中图分类号: 

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