• 综述 •
高耕, 张克宇, 王倩雯, 张利波, 崔丁方, 姚耀春. 金属草酸盐基负极材料——离子电池储能材料的新选择[J]. 化学进展, 2022, 34(2): 434-446.
Geng Gao, Keyu Zhang, Qianwen Wang, Libo Zhang, Dingfang Cui, Yaochun Yao. Metal Oxalate-Based Anode Materials: A New Choice for Energy Storage Materials Applied in Metal Ion Batteries[J]. Progress in Chemistry, 2022, 34(2): 434-446.
商业化锂离子电池石墨负极和锂盐过渡金属氧化物正极材料的储锂容量都已接近各自的理论值,探索下一代高能量密度电极材料是解决现阶段锂离子电池容量限制的关键。近年来,新型金属草酸基负极材料,借助其在金属离子电池中多元化储能机制诱发的较高储能效应在碱金属离子电池绿色储能材料领域备受关注。本文就金属草酸基材料在锂、钠、钾金属离子电池方面的最新研究进行了综述,着重介绍了材料的晶型结构、多元化储能机制及储能过程中的动力学特征,简单阐述了材料在电化学储能中存在的问题,分析了金属草酸基负极材料在形貌晶型控制、界面碳复合改性和金属元素掺杂方面的改性策略。最后,预测了金属草酸基负极材料在碱金属离子电池体系的发展方向。
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Metal oxalates | Theoretical capacity (mAh /g) | Coulombic efficiency (1st) | Long-term cycle behavior (capacity, cycle, current (A/g)) | Capacity retention | ref |
---|---|---|---|---|---|
MnC2O4 nanoribbon | 374.95 | 47.62% | 250 (100th, 1 C) | 23.81% | |
MnC2O4 microtubes | 374.95 | 48.10% | 990 (100th, 0.375) | 76.94% | |
FeC2O4 multilayer and mesoporous | 372.58 | 63.29% | 993.3 (200th, 1 C) | 65.30% | |
FeC2O4·2H2O(A-FCO-55) | 297.95 | 47.92% | 550 (300th, 0.5) | 36.26% | |
FeC2O4(A-FCO-300) | 372.58 | 72.22% | 1040 (300th, 0.5) | 72.22% | |
α@β-FeC2O4 | 372.58 | 79.86% | 1156.27 (500th, 0.5) | 72.69% | |
FeC2O4 concoons | 372.58 | - | 825 (100th, 1 C) | 63.95% | |
FeC2O4 rods | 372.58 | - | 906 (100th, 1 C) | 69.16% | |
FeC2O4·2H2O microrods | 372.58 | - | 346 (100th, 0.5 C) | 25.82% | |
FeC2O4 array | 372.58 | - | 1267 (200th, 0.756) | ||
CoC2O4 nanorods | 364.77 | 61.96% | 924 (100th, 0.05) | 57.43% | |
CoC2O4 nanorods | 364.77 | 62.16% | 959 (100th, 1 C) | 59.97% | |
CoC2O4 nanosheets | 364.77 | 64.89% | 741 (100th, 1 C) | 48.81% | |
Porous CoC2O4 nanorods | 364.77 | - | 1230 (100th, 0.5) | 80.60% | |
NiC2O4·2H2O nanorods | 293.32 | 67.70% | 578.9 (100th, 0.5) | 54% | |
NiC2O4 nanorods | 365.36 | 59.20% | 300 (100th, 0.5) | 42.86% | |
NiC2O4 nanoribbon | 365.36 | 67.00% | 250 (60th, 2 C) | 22.73% | |
CuC2O4·0.14H2O cylinder | 43.10% | 970 (100th, 0.2) | 105.40% | ||
CuC2O4·0.53H2O rod | 42.00% | 849.3 (100th, 0.2) | 70.11% | ||
CuC2O4·0.14H2O spherical | 57% | 1260.4 (100th, 0.2) | 87.77% | ||
CuC2O4·0.49H2O cotton | 37.60% | 1181.1 (100th, 0.2) | 69.93% | ||
CuC2O4·xH2O caky | 51.20% | 873 (100th, 0.1) | 106.59% | ||
ZnC2O4 nanoribbon | - | 200 (75th, 2 C) | 18.52% | ||
SnC2O4 | 46.00% | 170 (200th, 0.1) | 12.20% |
[1] |
Xu C F, Fang X, Zhan J, Chen J X, Liang F. Prog. Chem., 2020, 32(6): 836.
|
( 徐昌藩, 房鑫, 湛菁, 陈佳希, 梁风. 化学进展, 2020, 32(6): 836.)
doi: 10.7536/PC190924 |
|
[2] |
Li H, Wu C, Wu F, Bai Y, Acta Chimica Sinica, 2014, 72(01):21.
doi: 10.6023/A13080830 URL |
( 李慧, 吴川, 吴锋, 白莹. 化学学报, 2014, 72(01):21.)
|
|
[3] |
Liang S Z, Cheng Y J, Zhu J, Xia Y G, Müller-Buschbaum P. Small Methods, 2020, 4(8): 2000218.
doi: 10.1002/smtd.v4.8 URL |
[4] |
Liang Y R, Zhao C Z, Yuan H, Chen Y, Zhang W C, Huang J Q, Yu D S, Liu Y L, Titirici M M, Chueh Y L, Yu H J, Zhang Q. InfoMat, 2019, 1(1): 6.
doi: 10.1002/inf2.v1.1 URL |
[5] |
Fan E S, Li L, Wang Z P, Lin J, Huang Y X, Yao Y, Chen R J, Wu F. Chem. Rev., 2020, 120(14): 7020.
doi: 10.1021/acs.chemrev.9b00535 URL |
[6] |
Wang Y Q, Gu L, Guo Y G, Li H, He X Q, Tsukimoto S, Ikuhara Y, Wan L J. J. Am. Chem. Soc., 2012, 134(18): 7874.
doi: 10.1021/ja301266w URL |
[7] |
Ren H, Yu R B, Wang J Y, Jin Q, Yang M, Mao D, Kisailus D, Zhao H J, Wang D. Nano Lett., 2014, 14(11): 6679.
doi: 10.1021/nl503378a URL |
[8] |
Wang J, Zhou Y K, Hu Y Y, O’Hayre R, Shao Z P. J. Phys. Chem. C, 2011, 115(5): 2529.
doi: 10.1021/jp1087509 URL |
[9] |
Jin H C, Xin S, Chuang C H, Li W D, Wang H Y, Zhu J, Xie H Y, Zhang T M, Wan Y Y, Qi Z K, Yan W S, Lu Y R, Chan T S, Wu X J, Goodenough J B, Ji H X, Duan X F. Science, 2020, 370(6513): 192.
doi: 10.1126/science.aav5842 URL |
[10] |
Li C L, Liu C, Wang W, Mutlu Z, Bell J, Ahmed K, Ye R, Ozkan M, Ozkan C S. Sci. Rep., 2017, 7(1): 1.
doi: 10.1038/s41598-016-0028-x URL |
[11] |
Zuo X X, Zhu J, Müller-Buschbaum P, Cheng Y J. Nano Energy, 2017, 31: 113.
doi: 10.1016/j.nanoen.2016.11.013 URL |
[12] |
Yin X M, Li C C, Zhang M, Hao Q Y, Liu S, Chen L B, Wang T H. J. Phys. Chem. C, 2010, 114(17): 8084.
doi: 10.1021/jp100224x URL |
[13] |
Usui H, Kono T, Sakaguchi H. International Journal of Electrochemical ence, 2012, 7(5):4322.
|
[14] |
Bresser D, Mueller F, Fiedler M, Krueger S, Kloepsch R, Baither D, Winter M, Paillard E, Passerini S. Chem. Mater., 2013, 25(24): 4977.
doi: 10.1021/cm403443t URL |
[15] |
Kim M C, Kim S J, Han S B, Kwak D H, Hwang E T, Kim D M, Lee G H, Choe H S, Park K W. J. Mater. Chem. A, 2015, 3(45): 23003.
doi: 10.1039/C5TA05455A URL |
[16] |
Bell J, Ye R, Ahmed K, Liu C, Ozkan M, Ozkan C S. Nano Energy, 2015, 18: 47.
doi: 10.1016/j.nanoen.2015.09.013 URL |
[17] |
Liu H, Wang G X, Liu J, Qiao S Z, Ahn H. J. Mater. Chem., 2011, 21(9): 3046.
doi: 10.1039/c0jm03132a URL |
[18] |
Cao K Z, Jiao L F, Liu Y C, Liu H Q, Wang Y J, Yuan H T. Adv. Funct. Mater., 2015, 25(7): 1082.
doi: 10.1002/adfm.v25.7 URL |
[19] |
Ma Y, Liu P, Xie Q, Zhang C, Wang L, Peng D. Materials today energy (Materials Today Energy), 2020, 16:100383.
doi: 10.1016/j.mtener.2020.100383 URL |
[20] |
Fu C P, Mahadevegowda A, Grant P S. J. Mater. Chem. A, 2016, 4(7): 2597.
doi: 10.1039/C5TA09141A URL |
[21] |
Gao J, Lowe M A, Abruña H D. Chem. Mater., 2011, 23(13): 3223.
doi: 10.1021/cm201039w URL |
[22] |
Wang L B, Tang W J, Jing Y, Su L W, Zhou Z. ACS Appl. Mater. Interfaces, 2014, 6(15): 12346.
doi: 10.1021/am5021233 URL |
[23] |
Zhong Y R, Su L W, Yang M, Wei J P, Zhou Z. ACS Appl. Mater. Interfaces, 2013, 5(21): 11212.
doi: 10.1021/am403453r URL |
[24] |
Zhao S Q, Yu Y, Wei S S, Wang Y X, Zhao C H, Liu R, Shen Q. J. Power Sources, 2014, 253: 251.
doi: 10.1016/j.jpowsour.2013.12.055 URL |
[25] |
Zhou L K, Kong X H, Gao M, Lian F, Li B J, Zhou Z F, Cao H Q. Inorg. Chem., 2014, 53(17): 9228.
doi: 10.1021/ic501321z URL |
[26] |
Park J S, Jo J H, Yashiro H, Kim S S, Kim S J, Sun Y K, Myung S T. ACS Appl. Mater. Interfaces, 2017, 9(31): 25941.
doi: 10.1021/acsami.7b03325 URL |
[27] |
Shi S, Hua X, Guo H. Ceramics International (Ceramics International), 2018, 44(12):13495.
doi: 10.1016/j.ceramint.2018.04.179 URL |
[28] |
LÓpez M C, Tirado J L, PÉrez Vicente C. J. Power Sources, 2013, 227: 65.
doi: 10.1016/j.jpowsour.2012.08.100 URL |
[29] |
Qi Z Q, Wu Y D, Li X F, Qu Y, Yang Y Y, Mei D J. Ionics, 2020, 26(1): 33.
doi: 10.1007/s11581-019-03181-4 URL |
[30] |
Kang W P, Shen Q. J. Power Sources, 2013, 238: 203.
doi: 10.1016/j.jpowsour.2013.03.087 URL |
[31] |
Zhang Y H, Lu Z X, Guo M Q, Bai Z C, Tang B. JOM, 2016, 68(11): 2952.
doi: 10.1007/s11837-016-2126-4 URL |
[32] |
Ang W A, Cheah Y L, Wong C L, Prasanth R, Hng H H, Madhavi S. J. Phys. Chem. C, 2013, 117(32): 16316.
doi: 10.1021/jp404049f URL |
[33] |
Xu J M, He L, Liu H, Han T, Wang Y J, Zhang C J, Zhang Y H. Electrochimica Acta, 2015, 170: 85.
doi: 10.1016/j.electacta.2015.04.114 URL |
[34] |
Zhong Y. Doctoral Dissertation of Zhejiang University, 2016.
|
( 钟媛. 浙江大学博士论文, 2016.).
|
|
[35] |
Ang W A, Gupta N, Prasanth R, Madhavi S. ACS Appl. Mater. Interfaces, 2012, 4(12): 7011.
doi: 10.1021/am3022653 URL |
[36] |
Zhang K Y, Li Y, Wang Y K, Zhao J Y, Chen X M, Dai Y N, Yao Y C. Chem. Eng. J., 2020, 384: 123281.
doi: 10.1016/j.cej.2019.123281 URL |
[37] |
Zhang K Y, Li Y, Hu X J, Liang F, Wang L, Xu R H, Dai Y N, Yao Y C. Chem. Eng. J., 2021, 404: 126464.
doi: 10.1016/j.cej.2020.126464 URL |
[38] |
Zhang K Y, Liang F, Wang Y K, Dai Y N, Yao Y C. J. Alloys Compd., 2019, 779: 91.
doi: 10.1016/j.jallcom.2018.11.011 URL |
[39] |
Yang Y, He L, Lu J F, Liu Z Y, Wang N Y, Su J, Long Y F, Lv X, Wen Y X. Electrochimica Acta, 2019, 321: 134673.
doi: 10.1016/j.electacta.2019.134673 URL |
[40] |
Kim H, Choi W I, Jang Y, Balasubramanian M, Lee W, Park G O, Park S B, Yoo J, Hong J S, Choi Y S, Lee H S, Bae I T, Kim J M, Yoon W S. ACS Nano, 2018, 12(3): 2909.
doi: 10.1021/acsnano.8b00435 URL |
[41] |
Huang X L, Chai J, Jiang T, Wei Y J, Chen G, Liu W Q, Han D X, Niu L, Wang L M, Zhang X B. J. Mater. Chem., 2012, 22(8): 3404.
doi: 10.1039/c2jm15377g URL |
[42] |
Pramanik A, Maiti S P, Mahanty S. Sciense Letters, 2015, 4:104.
|
[43] |
Li B J, Cao H Q, Shao J, Zheng H, Lu Y X, Yin J F, Qu M Z. Chem. Commun., 2011, 47(11): 3159.
doi: 10.1039/c0cc04507a URL |
[44] |
Inamdar A I, Chavan H S, Aqueel Ahmed A T, Jo Y, Cho S, Kim J, Pawar S M, Kim H, Im H. J. Alloys Compd., 2020, 829: 154593.
doi: 10.1016/j.jallcom.2020.154593 URL |
[45] |
Pramanik A, Maiti S, Mahanty S. J. Mater. Chem. A, 2014, 2(43): 18515.
doi: 10.1039/C4TA03379E URL |
[46] |
AragÓn M J, LeÓn B, PÉrez Vicente C, Tirado J L. Inorg. Chem., 2008, 47(22): 10366.
doi: 10.1021/ic8008927 URL |
[47] |
Ang W A E, Cheah Y L, Wong C L, Hng H H, Madhavi S. J. Alloys Compd., 2015, 638: 324.
doi: 10.1016/j.jallcom.2015.02.203 URL |
[48] |
Baran E J, Monje P V. Met. Ions Life Sci. 2008, 8: 219.
|
[49] |
Baran E J. J. Coord. Chem., 2014, 67(23/24): 3734.
doi: 10.1080/00958972.2014.937340 URL |
[50] |
Krishnamurty K V, Harris G M. Chem. Rev., 1961, 61(3): 213.
doi: 10.1021/cr60211a001 URL |
[51] |
Lenchev A, Trifonova E P. Cryst. Res. Technol., 1990, 25(9): 1017.
doi: 10.1002/(ISSN)1521-4079 URL |
[52] |
Molinier M, Price D J, Wood P T, Powell A K. J. Chem. Soc., Dalton Trans., 1997(21): 4061.
|
[53] |
Jo C H, Yashiro H, Yuan S, Shi L Y, Myung S T. ACS Appl. Mater. Interfaces, 2018, 10(47): 40523.
doi: 10.1021/acsami.8b13641 URL |
[54] |
Barazorda-Ccahuana H L, Nedyalkova M, Kichev I, Madurga S, Donkova B, Simeonov V. ACS Omega, 2020, 5(16): 9071.
doi: 10.1021/acsomega.9b03434 pmid: 32363259 |
[55] |
Su Y Z, Chen H Y, Hu Z X, Liu S N, Xiao L H, Jiang M. Journal of Central South University(Science and Technology), 2013, 44(06):2237.
|
( 苏玉长, 陈宏艳, 胡泽星, 刘赛男, 肖立华, 江敏. 中南大学学报(自然科学版), 2013, 44(06):2237.)
|
|
[56] |
Nie L C. Master's Dissertation of Zhejiang University, 2014.
|
( 聂林才. 上海大学硕士论文, 2014.).
|
|
[57] |
Zhang K Y, Xu R H, Wei R H, Li Y, Wang Y K, Zhang Y N, Dai Y N, Yao Y C. Mater. Chem. Phys., 2020, 243: 122676.
doi: 10.1016/j.matchemphys.2020.122676 URL |
[58] |
Yeoh J S, Armer C F, Lowe A. Mater. Today Energy, 2018, 9: 198.
|
[59] |
Oh H J, Jo C H, Yoon C S, Yashiro H, Sun J K, Passerini S, Sun YK, Myung S T. NPG Asia materials. 2016, 8(5):270.
|
[60] |
Zhang Y, Wang C, Dong Y, Wei R, Zhang J. Chem.-A Eur. J., 2021, 27(3):993.
doi: 10.1002/chem.v27.3 URL |
[61] |
Zhang K Y, Gao G, Li Y, Wang Y K, Xu R H, Dai Y N, Yao Y C. Mater. Lett., 2020, 266: 127476.
doi: 10.1016/j.matlet.2020.127476 URL |
[62] |
AragÓn M J, LeÓn B, PÉrez Vicente C, Tirado J L, Chadwick A V, Berko A, Beh S Y. Chem. Mater., 2009, 21(9): 1834.
doi: 10.1021/cm803435p URL |
[63] |
LeÓn B, Vicente C P, Tirado J L. Solid State Ion., 2012, 225: 518.
doi: 10.1016/j.ssi.2011.12.012 URL |
[64] |
AragÓn M J, LeÓn B, Serrano T, PÉrez Vicente C, Tirado J L. J. Mater. Chem., 2011, 21(27): 10102.
doi: 10.1039/c0jm03880f URL |
[65] |
Wu X H, Guo J H, McDonald M J, Li S G, Xu B B, Yang Y. Electrochimica Acta, 2015, 163: 93.
doi: 10.1016/j.electacta.2015.02.134 URL |
[66] |
Li Q, Li H S, Xia Q T, Hu Z Q, Zhu Y, Yan S S, Ge C, Zhang Q H, Wang X X, Shang X T, Fan S T, Long Y Z, Gu L, Miao G X, Yu G H, Moodera J S. Nat. Mater., 2021, 20(1): 76.
doi: 10.1038/s41563-020-0756-y URL |
[67] |
Yu L P, Zhou X H, Lu L, Wu X L, Wang F J. ChemSusChem, 2020, 13(20): 5361.
doi: 10.1002/cssc.v13.20 URL |
[68] |
Lu X X, Mao Q N, Chen Y F, Bao L, Tong L C, Xiong Q Q, Qin H Y, Pan H G, Ji Z G. Electrochimica Acta, 2018, 282: 351.
doi: 10.1016/j.electacta.2018.06.069 URL |
[69] |
Taberna P L, Mitra S, Poizot P, Simon P, Tarascon J M. Nat. Mater., 2006, 5(7): 567.
pmid: 16783360 |
[70] |
Pang H, Wang S, Li X, Zhao S, Li S. International Journal of Electrochemical Science, 2013, 8(3):4174.
|
[71] |
Hu Y N, Lin Z H, Min F X, Teng F, Wu H M, Wang S Q, Liu J W, Feng C Q. J. Nanosci. Nanotechnol., 2020, 20(3): 1740.
doi: 10.1166/jnn.2020.17139 URL |
[72] |
Feng F, Kang W P, Yu F Q, Zhang H, Shen Q. J. Power Sources, 2015, 282: 109.
doi: 10.1016/j.jpowsour.2015.02.043 URL |
[73] |
Deng J T, Wang L, Deng J, Fang Y, Lin Y, Hu Y H. J. Mater. Chem. A, 2020, 8(6): 3397.
doi: 10.1039/C9TA10982J URL |
[74] |
Zhang K Y, Zhang D, Li Y, Wang L, Liang F, Dai Y N, Yao Y C. Appl. Surf. Sci., 2020, 507: 145051.
doi: 10.1016/j.apsusc.2019.145051 URL |
[75] |
Li L, Zheng Y, Zhang S L, Yang J P, Shao Z P, Guo Z P. Energy Environ. Sci., 2018, 11(9): 2310.
doi: 10.1039/C8EE01023D URL |
[76] |
Wu X Y, Leonard D P, Ji X L. Chem. Mater., 2017, 29(12): 5031.
doi: 10.1021/acs.chemmater.7b01764 URL |
[77] |
Irisarri E, Ponrouch A, Palacin M R. J. Electrochem. Soc., 2015, 162(14): A2476.
doi: 10.1149/2.0091514jes URL |
[78] |
Ramireddy T, Sharma N, Xing T, Chen Y, Leforestier J, Glushenkov A M. ACS Appl. Mater. Interfaces, 2016, 8(44): 30152.
doi: 10.1021/acsami.6b09619 URL |
[79] |
Li C L, Chen K Y, Zhou X J, Maier J. Npj Comput. Mater., 2018, 4(1): 1.
doi: 10.1038/s41524-017-0060-9 URL |
[80] |
Lu Y C, Ma C Z, Alvarado J, Kidera T, Dimov N, Meng Y S, Okada S. J. Power Sources, 2015, 284: 287.
doi: 10.1016/j.jpowsour.2015.03.042 URL |
[81] |
Vaalma C, Buchholz D, Passerini S. Curr. Opin. Electrochem., 2018, 9: 41.
|
[82] |
Hosaka T, Kubota K, Hameed A S, Komaba S. Chem. Rev., 2020, 120(14): 6358.
doi: 10.1021/acs.chemrev.9b00463 URL |
[83] |
Ju Z C, Li P Z, Ma G Y, Xing Z, Zhuang Q C, Qian Y T. Energy Storage Mater., 2018, 11: 38.
|
[84] |
Chen Z, Yin D G, Zhang M. Small, 2018, 14(17): 1703818.
doi: 10.1002/smll.v14.17 URL |
[85] |
Li D P, Zhu M, Chen L N, Chen L, Zhai W, Ai Q, Hou G M, Sun Q, Liu Y, Liang Z, Guo S R, Lou J, Si P C, Feng J K, Zhang L, Ci L J. Adv. Mater. Interfaces, 2018, 5(15): 1800606.
doi: 10.1002/admi.v5.15 URL |
[86] |
Wang L F, Wei K Y, Zhang P J, Wang H, Qi X J, Wu X, Zhao W, Ju Z C. J. Nanosci. Nanotechnol., 2019, 19(6): 3610.
doi: 10.1166/jnn.2019.16106 URL |
[87] |
Jo C H, Jo J H, Choi J U, Yashiro H, Kim H, Myung S T. ACS Sustainable Chem. Eng., 2020, 8(9): 3743.
doi: 10.1021/acssuschemeng.9b06951 URL |
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