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化学进展 2016, Vol. 28 Issue (12): 1860-1869 DOI: 10.7536/PC160731 前一篇   后一篇

• 综述与评论 •

菱沸石在柴油车尾气NOx催化净化中的应用

谢利娟1,2, 石晓燕3,4, 刘福东3,4, 阮文权1,2*   

  1. 1. 江南大学环境与土木工程学院 无锡 214122;
    2. 江苏省厌氧生物技术重点实验室 无锡 214122;
    3. 中国科学院生态环境研究中心 北京 100085;
    4. 中国科学院大学 北京 100049
  • 收稿日期:2016-07-01 修回日期:2016-10-01 出版日期:2016-12-25 发布日期:2016-12-23
  • 通讯作者: 阮文权,e-mail:wqruan@jiangnan.edu.cn E-mail:wqruan@jiangnan.edu.cn
  • 基金资助:
    国家自然科学基金项目（No.51508231，51278486）和中央高校基本科研业务费专项资金（JUSRP11524）资助
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Selective Catalytic Reduction of NOx from Diesel Engine with NH3 over Zeolites Catalysts with Chabazite

Xie Lijuan1,2, Shi Xiaoyan3,4, Liu Fudong3,4, Ruan Wenquan1,2*   

  1. 1. School of Environment and Civil Engineering, Jiangnan University, Wuxi 214122;
    2. Jiangsu Key Laboratory of Anaerobic Biotechnology, Wuxi 214122, China;
    3. Research Center for Eco-environmental Science, Chinese Academy of Sciences, Beijing 100085, China;
    4. University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2016-07-01 Revised:2016-10-01 Online:2016-12-25 Published:2016-12-23
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No.51508231, 51278486) and the Fundamental Research Funds for the Central Universities (JUSRP11524).
柴油车尾气NOx控制是目前大气污染控制领域的重要研究内容，对改善城市大气污染现状有着极其重要的作用。NH3选择性催化还原NOx（NH3-SCR）是应用于该领域的主流技术之一。近年来，以具有菱沸石（chabazite，CHA）结构的分子筛为载体负载Cu制备的Cu-CHA（Cu-SSZ-13和Cu-SAPO-34）系列催化剂，因其优秀的NH3-SCR活性和良好的水热稳定性，成为学者们关注的热点。本文首先从制备方法及反应条件对Cu-CHA催化性能的影响和NH3-SCR反应机理这几个方面系统阐述Cu基菱沸石在柴油车尾气NOx催化净化领域的研究进展；然后总结了负载其他过渡金属和稀土金属制备的M-CHA分子筛催化剂在NH3-SCR反应中的应用，指出双活性中心菱沸石催化剂在NH3-SCR领域表现出的优势；在此基础上对菱沸石NH3-SCR催化剂的进一步改良做出展望。
关键词： NOx控制, NH3选择性催化还原, 菱沸石, 反应机理, 双活性中心
The purification of NOx from diesel engine exhaust is an important topic in the field of air pollution control, which is significant for the improvement of current unban air quality. The selective catalytic reduction of NOx with NH3 (NH3-SCR) is one of the most promising technologies for the control of NOx emission from diesel engine exhaust. In recent years, Cu-CHA catalysts, which are obtained from loading transition metal Cu on zeolites with chabazite (CHA) structure, have attracted much attention in the field of NH3-SCR reaction, due to their excellent NH3-SCR activity and hydrothermal stability. Cu-SSZ-13 and Cu-SAPO-34 are the two typical Cu-CHA catalysts. In this review, the progress of NOx control in the field of diesel engine exhaust with Cu-CHA catalysts is stated from three aspects firstly, including the influences of preparation method, the effects of reaction condition and the NH3-SCR reaction mechanism. Then, the application of M-CHA catalysts in NH3-SCR reaction are elaborated, where M is limited as some other transition metal and rare earth metal. Meanwhile, the advantages of bimetallic-based CHA zeolites in NH3-SCR reaction are identified. Based on these results, the possible improvement orientations for NH3-SCR catalysts with CHA zeolites structure are also prospected.

Contents
1 Introduction
2 Application of Cu-CHA catalysts in NH3-SCR
2.1 Cu-SSZ-13 used for NOx purification
2.2 Cu-SAPO-34 used for NOx purification
3 Application of Fe-CHA catalysts in NH3-SCR
4 Application of bimetallic active center catalysts with CHA structure in NH3-SCR
5 Conclusion and outlook

Key words: NOx control, selective catalytic reduction of NH3, chabazite, reaction mechanism, bimetallic active center

中图分类号: 

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