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化学进展 2014, Vol. 26 Issue (11): 1811-1820 DOI: 10.7536/PC140703 前一篇   后一篇

• 综述与评论 •

嵌段共聚物结晶性胶束

杨洁心, 刘雷, 徐君庭*   

  1. 浙江大学高分子科学与工程学系 杭州 310027
  • 收稿日期:2014-07-01 修回日期:2014-08-01 出版日期:2014-11-15 发布日期:2014-09-12
  • 通讯作者: 徐君庭 E-mail:xujt@zju.edu.cn
  • 基金资助:

    国家自然科学基金项目(No. 21274130)资助

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Crystalline Micelles of Block Copolymers

Yang Jiexin, Liu Lei, Xu Junting*   

  1. Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
  • Received:2014-07-01 Revised:2014-08-01 Online:2014-11-15 Published:2014-09-12
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No. 21274130)

近年来嵌段共聚物在选择性溶剂中由结晶驱动形成胶束的自组装过程因其较好的可控性逐渐受到人们的关注.本文首先综述了嵌段共聚物结晶性胶束形貌和尺寸的影响因素,包括溶剂环境、共聚物结构、结晶温度等.然后介绍了结晶性胶束的活性生长以及"嵌段共胶束";最后提出了该研究领域目前存在的问题和今后可能的发展方向.

关键词： 嵌段共聚物, 结晶, 自组装, 胶束

Recently the crystallization-driven self-assembly of block copolymers into semicrystalline micelles in the selective solvent has been paid increasing attention due to the good controllability. In this paper we first review some factors controlling the morphology and size of the semicrystalline micelles of block copolymers, including solvent quality, structure of block copolymers, and crystallization temperature. The living growth of semicrystalline micelles with time and formation of "block co-micelles" using micelles as building blocks are also introduced. Finally, currently existing problems and outlook in this field are discussed.

Contents
1 Introduction
2 Morphologies of block copolymer crystalline micelles
2.1 Effect of chain structure of block copolymer
2.2 Effect of solvent quality
2.3 Effect of crystallization temperature
3 Living growth of block copolymer crystalline micelles
4 Block co-micelles
5 Conclusion and outlook

Key words: block copolymer, crystallization, self-assembly, micelle

中图分类号: 

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摘要

嵌段共聚物结晶性胶束