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化学进展 2009, Vol. 21 Issue (10): 2053-2059 前一篇   后一篇

• 综述与评论 •

超顺磁性纳米颗粒为催化剂载体的研究*

王志飞1**; 杨雯2; 何农跃3   

  1. （1.东南大学化学化工学院 南京 211189；2.空军驻沪宁地区代表室 南京 210013；3.东南大学生物电子国家重点实验室 南京 210096）
  • 收稿日期:2008-11-03 修回日期:2009-02-14 出版日期:2009-10-24 发布日期:2009-10-09
  • 通讯作者: 王志飞 E-mail:zfwang@seu.edu.cn
  • 基金资助:

    国家自然科学基金

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The Catalyst with the Superparamagnetic Nanoparticles as Its Supporter

Wang Zhifei1**; Yang Wen2; He Nongyue3   

  1.  (1. School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China; 2. Military Representation Office of Air Force in Hu-Ning District, Nanjing 210013, China; 3. State Key Laboratory of Bioelectronics, Southeast University, Nanjing 210096, China)
  • Received:2008-11-03 Revised:2009-02-14 Online:2009-10-24 Published:2009-10-09
  • Contact: Wang Zhifei E-mail:zfwang@seu.edu.cn
  • Supported by:

    National Natural Science Foundation of China

如何结合催化剂的制备找到一条新的催化剂分离与回收途径，已成为均相催化剂以及近十年快速发展的纳米催化剂研究中的一项重要内容。近年来，基于超顺磁性纳米颗粒作为催化剂载体来制备新型纳米催化剂的工作因此受到广泛关注。利用超顺磁性纳米颗粒所提供的磁学特性进行磁分离，不仅有效地解决了分离与重复使用问题，而且因其尺度处于纳米级，保持了以上催化剂的高活性、高选择性等动力学优点。本文从超顺磁性纳米载体的制备、催化剂的制备与活性评价等角度对近几年的研究工作进行综述，并对其发展前景进行展望。

关键词： 超顺磁性, 纳米颗粒, 催化剂载体, 分离与回收

As far as the homogeneous catalyst or nano catalyst developed quickly in the past decade is concerned, it is one of the main research topics to find the new procedure to separate and recycle them out of the reaction mixture in combination with their preparation. Considering the above background, many related researches on the application of the superparamagnetic nanoparticle as the catalyst supporter have been conducted recently. Compared to their parent catalysts in solution, the magnetic nanoparticle-supported catalytic species not only allow facile seperation and recycling of the catalyst under the extern magnetic field, but also keep their previous dynamic performance such as high activity and selectivity due to the body size under the nano meter scale. In this paper, the preparation of the superparamagnetic particle as the catalyst supporter as well as the catalytic activity is reviewed, and the direction of the further research is suggested.

Contents
1 Introduction
2 Preparation of superparamagnetic nano supporter
2.1 Preparation of C/NiFe nanoparticle
2.2 Preparation of γ-Fe2O3、Fe3O4、NiFe2O3 nanoparticles and so on
2.3 Preparation of SiO2/Fe2O3 nanoparticle
2.4 Preparation of polymer/Fe2O3 nanoparticle
3 Preparation of catalyst and test of catalytic activity
3.1 Acid and base catalyst
3.2 Noble metal catalyst
3.3 Chiral catalyst
3.4 Transition metal coordination catalyst
3.5 Enzyme
3.6 Other catalysts
4 Conclusion and prospects

Key words: superparamagnetic, nanoparticle, catalyst supporter, separation and recycle

中图分类号: 

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