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化学进展 2009, Vol. 21 Issue (04): 622-628 前一篇   后一篇

• 综述与评论 •

贵金属助剂对费-托合成用钴基催化剂的促进作用*

张辉; 储伟*   

  1. (四川大学化学工程学院 成都 610065)
  • 收稿日期:2008-05-09 修回日期:2008-07-22 出版日期:2009-04-24 发布日期:2009-04-03
  • 通讯作者: 储伟 E-mail:chuwei65@yahoo.com.cn
  • 基金资助:

    国家自然科学基金

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Effects of Noble Metal Promoter on Supported Cobalt-Based Fischer-Tropsch Catalysts

Zhang Hui;  Chu Wei **   

  1. (Department of Chemical Engineering, Sichuan University, Chengdu 610065, China)
  • Received:2008-05-09 Revised:2008-07-22 Online:2009-04-24 Published:2009-04-03
  • Contact: Chu Wei E-mail:chuwei65@yahoo.com.cn

贵金属助剂促进的费-托合成用钴基催化剂具有高活性和长链烃(C5+)选择性优越等特点，被广泛应用于由合成气制清洁燃料的合成反应中。 本文重点讨论了贵金属助剂对活性钴物种的结构（还原度、分散度、双金属颗粒或合金的构成）, 钴基催化剂稳定性以及其对费-托合成的反应速率和产物选择性的影响规律。

关键词： 费-托合成, 钴基催化剂, 贵金属助剂, 还原度, 分散度

Being of high activity and good selectivity in C5+ hydrocarbons, noble metal promoted cobalt Fischer-Tropsch catalysts are widely utilized in carbon monoxide hydrogenation to clean fuels or long chain hydrocarbons. The effects of noble metal promoter on the structure of Co active species are reviewed and discussed in this paper, as well as the reducibility, dispersion, the formation of bimetallic particles or alloy, and the influences on their catalytic performances.

Contents
1 Introduction
2 Effects of noble metal promoter on supported cobalt catalysts
2.1 Reducibility of FT cobalt catalysts promoted by noble metal
2.2 Dispersion of noble metal promoted nano-cobalt catalysts
2.3 Formation and effects of bimetallic cobalt-noble metal FT catalysts
3 Effects of noble metal on the deactivation behaviors of promoted FT cobalt catalysts
4 Effects of noble metal addition on the Fischer-Tropsch performances and product distribution
5 Summary

Key words: Fischer-Tropsch synthesis, cobalt catalysts, noble metal promoters, reducibility, dispersion

中图分类号: 

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[ 1 ] 　Khodakov A , Chu W, Fongarland P. Chem. Rev. , 2007 , 107 :1692 —1744
[ 2 ] 　Chu W, Wang L N , Khodakov A , et al . Angew. Chem. Int . Ed. ,2008 , 47 : 5052 —5055
[ 3 ] 　Dry M E. Catal . Today , 2002 , 71 : 227 —241
[ 4 ] 　Chen J G, Sun Y H. Stud. Surf . Sci . Catal . , 2004 , 147 : 277 —282
[ 5 ] 　朱拓权(Zhu T Q) , 房克功(Fang K G) , 陈建刚(Chen J G) 等.燃料化学学报(J . Fuel Chem. Technol . ) , 2005 , 33 (4) : 506 —508
[ 6 ] 　Zhang Y, Hanayama K, Tsubaki N. Catal . Commun. , 2006 , 7 :251 —254
[ 7 ] 　Zhang J L , Chen J G, Ren J , et al . Appl . Catal . A , 2003 , 243 :121 —133
[ 8 ] 　Wang T, Ding Y J , Xiong J M, et al . Stud. Surf . Sci . Catal . ,2004 , 147 : 349 —354
[ 9 ] 　Xiong H , Zhang Y, Liew K, et al . J . Mol . Catal . A , 2005 , 231 :145 —151
[10 ] 　徐慧远(Xu H Y) , 储伟(Chu W) , 慈志敏(Ci Z M) . 物理化学学报(Acta Phys. Chim. Sinica) , 2007 , 23 (7) : 1042 —1046
[11 ] 　Chu W, Hong J P , Dai X Y, et al . Chin. J . Chem. Phys. , 2007 ,20 : 743 —747
[12 ] 　Chu W, Kieffer R , Kiennemann A , Hindermann J P. Appl . Catal .A , 1995 , 121 : 95 —111
[13 ] 　Jacobs G, Das T K, Patterson P M, et al . Appl . Catal . A , 2003 ,247 : 335 —343
[14 ] 　Hilmen A M, Schanke D , Hanssen K F , et al . Appl . Catal . A ,1999 , 186 : 169 —188
[15 ] 　Shi L H , Chen J G, Fang K G, et al . Fuel , 2008 , 87 : 521 —526
[16 ] 　Chang J , Chen J G, Teng B T, et al . Chin. J . Catal . , 2005 , 26 :731 —733
[17 ] 　杨文书(Yang W S) , 房鼎业( Fang D Y) , 相宏伟(Xiang H W)等. 化学学报(Acta. Chim. Sinica) , 2005 , 63 (2) : 157 —162
[18 ] 　Ma W P , Ding YJ , Lin L W. Ind. Eng. Chem. Res. , 2004 , 43 :2391 —2398
[19 ] 　Iglesia E , Soled S L , Fiato R A. US 4822824 , 1989
[20 ] 　Alarion F , Deves J M, Euzen P. US 6007700 , 1999
[21 ] 　Eri S , Goodwin J G, George M, Riis T. US 4801573 , 1989
[22 ] 　Kobylinski T P , Kibby C L , Pannell R B , Eddy EL. US 4605676 ,1986
[23 ] 　Tristantini D , Lêgdberg S , Gevert B , et al . Fuel Process. Technol . ,2007 , 88 : 643 —649
[24 ] 　Batley G E , Ekstrom A , Johnson D A. J . Catal . , 1975 , 34 : 368 —375
[25 ] 　Pankina G V , Chernavskii P A , Khodakov A Y, et al . Russ. J .Phys. Chem. , 2006 , 80 : 732 —737
[26 ] 　Jacobs G, Chaney J A , Patterson P M, et al . Appl . Catal . A ,2004 , 264 : 203 —212
[27 ] 　Bianchi C L. Catal . Lett . , 2001 , 76 : 155 —159
[28 ] 　Li J L , Zhan X D , Zhang Y Q , et al . Appl . Catal . A , 2002 , 228 :203 —212
[29 ] 　Kogelbauer A , Goodwin J G, Oukaci R , et al . J . Catal . , 1996 ,160 : 125 —133
[30 ] 　Girardon J S , Constant-Griboval A , Gengembre L , et al . Catal .Today , 2005 , 106 : 161 —165
[31 ] 　Chu W, Chernavskii P A , Gengembre L , et al . J . Catal . , 2007 ,252 : 215 —230
[32 ] 　Schanke D , Vada S , Blekkan E A , et al . J . Catal . , 1995 , 156 :85 —95
[33 ] 　Jacobs G, Das T K, Zhang Y Q , et al . Appl . Catal . A , 2002 ,233 : 263 —281
[34 ] 　Tsubaki N , Sun S , Fujimoto K. J . Catal . , 2001 , 199 : 236 —246
[35 ] 　Sun S , Fujimoto K, Yoneyama Y, et al . Fuel , 2002 , 81 : 1583 —1591
[36 ] 　Qiu X, Tsubaki N , Sun S , et al . Fuel , 2002 , 81 : 1625 —1630
[37 ] 　Mauldin C H , Varnado D E. Stud. Surf . Sci . Catal . , 2001 , 136 :417 —422
[38 ] 　Girardon J-S , Quinet E , Khodakov A Y, et al . J . Catal . , 2007 ,248 : 143 —157
[39 ] 　Jongsomjit B , Panpranot J , Goodwin J G. J . Catal . , 2001 , 204 :98 —109
[40 ] 　Jacobs G, Patterson P M, Zhang Y, et al . Appl . Catal . A , 2002 ,233 : 215 —226
[41 ] 　Bezemer GL , Bitter J H , De Jong K, et al . J . Am. Chem. Soc. ,2006 , 128 : 3956 —3964
[42 ] 　Van Berge P J , van de Loosdrecht J , Barradas S , et al . Catal .Today , 2000 , 58 : 321 —334
[43 ] 　Dees MJ , Ponec V. J . Catal . , 1989 , 119 : 376 —387
[44 ] 　徐东彦(Xu D Y) , 李文钊(Li WZ) , 段洪敏(Duan HM) . 催化学报(Chinese Journal of Catalysis) , 2005 , 26 (9) : 780 —784
[45 ] 　Xu D Y, Li W Z, Duan H M, et al . Catal . Lett . , 2005 , 102 :229 —235
[46 ] 　Ojeda M, López Granados M, Rojas S , et al . J . Mol . Catal . A ,2003 , 202 : 179 —186
[47 ] 　Carlsson A F , Naschitzki M, Ba? umer M, et al . J . Phys. Chem. B ,2003 , 107 : 778 —785
[48 ] 　Nowitzki T, Carlsson A F , Martyanov O , et al . J . Phys. Chem. C ,2007 , 111 : 8566 —8572
[49 ] 　Rygh L E S , Nielsen C J . J . Catal . , 2000 , 194 : 401 —409
[50 ] 　Bardi U , Beard B C , Roos P N , J . Catal . , 1990 , 124 : 22 —29
[51 ] 　Pankina GV , Chernavskii P A , Krylova A Y, et al . Kinet . Catal . ,2007 , 48 : 567 —571
[52 ] 　Bazin D , Guczi L. Stud. Surf . Sci . Catal . , 2004 , 147 : 343 —348
[53 ] 　Bazin D , Kovàcs I , Lynch J , et al . Appl . Catal . A , 2003 , 242 :179 —186
[54 ] 　Guczi L , Bazin D , Kovàcs I , et al . Stud. Surf . Sci . Catal . , 2001 ,136 : 111 —116
[55 ] 　Jacobs G, Ji Y Y, Davis B H , et al . Appl . Catal . A , 2007 , 333 :177 —191
[56 ] 　Mierzw B , Kaszkur Z, Moraweck B , et al . J . Alloys Compd. ,1999 , 286 : 93 —97
[57 ] 　Saib A M, Borgna A , van de Loosdrecht J , et al . Appl . Catal . A ,2006 , 312 : 12 —19
[58 ] 　R? nningM, Nicholson D G, Holmen A. Catal . Lett . , 2001 , 72 :141 —146
[59 ] 　Li P , Liu J , Nag N , et al . Appl . Catal . A , 2006 , 307 : 212 —221
[60 ] 　Guczi L , Bazin D , Kovacs I , et al . Top. Catal . , 2002 , 2 : 129 —139
[61 ] 　Guczi L. Catal . Today , 2005 , 101 : 53 —64
[62 ] 　Bazin D , BorkóL , Koppány Z, et al . Catal . Lett . , 2002 , 84 :169 —182
[63 ] 　周玮(Zhou W) , 房克功(Fang J G) , 陈建刚(Chen J G) , 孙予罕(Sun Y H) . 化学进展(Progress in Chemistry) , 2006 , 18 (1) :45 —50
[64 ] 　Das T K, Jacobs G, Davis B. H. Catal . Lett . , 2005 , 101 : 187 —190
[65 ] 　Iglesia E , so led SL , Rocco A F. J . Catal . , 1992 , 137 : 212 —224
[66 ] 　Huber GW, Butala S J M, Lee M L , et al , Catal . Lett . , 2001 ,74 : 45 —48
[67 ] 　Madon R J , Reyes S C , Iglesia E. J . Phys. Chem. , 1991 , 95 :7795 —7804
[68 ] 　Iglesia E , Reyes S C , Madon R J , J . Catal . , 1991 , 129 : 238 —256
[69 ] 　Madon R J , Iglesia E. J . Catal . , 1993 , 139 : 576 —590
[70 ] 　Kogelbauer A , Goodwin J G, Oukaci R. J . Catal . , 1996 , 160 :125 —133
[71 ] 　Iglesia E. Appl . Catal . A , 1997 , 161 : 59 —78
[72 ] 　Li J L , Jacobs G, Zhang YQ , et al . Appl . Catal . A , 2002 , 223 :195 —203
[73 ] 　Schanke D , Vada S , Blekkan E A , et al . J . Catal . , 1995 , 156 :85 —95
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