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化学进展 2011, Vol. 23 Issue (9): 1936-1944 前一篇   后一篇

• 综述与评论 •

环糊精分子管道的制备与应用研究进展

张林1*, 李琳玲1, 程丽华2, 陈欢林1   

  1. 1. 浙江大学化学工程与生物工程学系教育部膜与水处理技术工程中心 杭州 310027;
    2. 浙江大学环境与资源学院 杭州 310027
  • 收稿日期:2010-12-01 修回日期:2011-01-01 出版日期:2011-09-24 发布日期:2011-09-02
  • 通讯作者: 张林 E-mail:linzhang@zju.edu.cn
  • 基金资助:

    国家自然科学基金项目(No.20946003)和中央高校基本科研业务费专项资金项目资助

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Progress of Preparation and Application of Cyclodextrin-based Molecular Tube

Zhang Lin1*, Li Linling1, Cheng Lihua2, Chen Huanlin1   

  1. 1. Engineering Research Center of Membrane and Water Treatment Technology, Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;
    2. College of Environment and Resource Sciences, Zhejiang University, Hangzhou 310027, China
  • Received:2010-12-01 Revised:2011-01-01 Online:2011-09-24 Published:2011-09-02

环糊精分子管道是一种基于环糊精制备的中空管状聚合物,因其特殊的空腔结构及与客体分子间的选择性组装现象而引起广泛关注。本文综述和比较了环糊精分子管道的主要制备方法,着重阐述了环糊精分子管道与客体分子间的选择性组装现象、机理及影响因素方面的研究成果。对环糊精分子管道的应用现状和潜在的应用价值进行了概括,最后提出了应予以重视的研究方向。

关键词： 环糊精, 分子管道, 包结作用, 自组装超分子结构

Cyclodextrin-based molecular tube is a hollow tubular polymer synthesized by threaded cyclodextrins. Recently, it has received extensive attention since its tubular molecular structure and selective inclusion complexation characteristic with various guest molecules including small molecules and polymers. In this paper, the main properties of cyclodextrin-based molecular tube are introduced and the preparation methods are reviewed in detail and compared with each other. The research about the selective inclusion complexation between molecular tube and guest molecules is elaborated, which include long-chain aliphatic and aromatic compounds. The assembling mechanism and influencing factors of complexation are discussed later. The recent applications of molecular tube in self-assembled monolayers, artificial chaperone and potential applications in constructing of novel self-assembly supramolecular architecture are summarized. Finally, the future research directions and problems in this area are prospected.

Contents
1 Introduction
2 Preparation of cyclodextrin-based molecular tube
3 Inclusion complexation characteristic of cyclod-extrin-based molecular tube
3.1 α-CD Molecular tube's selective inclusion compl-exation with long-chain aliphatic compounds
3.2 α-CD Molecular tube's selective inclusion compl-exation with long-chain aromatic compounds
4 Studies on application of α-CD molecular tube
5 Mechanism and influencing factors of inclusion complexation between guest Molecular and α-CD molecular tube
6 Conclusions and outlook

Key words: cyclodextrin, molecular tube, inclusion complexation, self-assembly supramolecular architecture

中图分类号: 

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